石油炼制与化工 ›› 2019, Vol. 50 ›› Issue (1): 37-41.

• 加工工艺 • 上一篇    下一篇

溶剂抽提-选择性加氢脱硫组合技术的开发及工业应用

张登前,唐文成,习远兵,褚阳,潘光成,戴立顺,李明丰   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2018-05-22 修回日期:2018-07-04 出版日期:2019-01-12 发布日期:2019-01-29
  • 通讯作者: 张登前 E-mail:zhangdengqian.ripp@sinopec.com
  • 基金资助:
    国家重点研发计划

DEVELOPMENT AND INDUSTRIAL APPLICATION OF SOLVENT EXTRACTION- SELECTIVE HYDRODESULFURIZATION COMBINATION TECHNOLOGY

  1.  
  • Received:2018-05-22 Revised:2018-07-04 Online:2019-01-12 Published:2019-01-29
  • Contact: Zhang Dengqian E-mail:zhangdengqian.ripp@sinopec.com
  • Supported by:
     

摘要: 针对以硫含量和烯烃含量高、芳烃含量低的催化裂化汽油为原料加氢脱硫生产满足车用汽油(Ⅴ)标准的汽油(简称国Ⅴ标准汽油)时辛烷值损失偏大的问题,开发了催化裂化汽油溶剂抽提-选择性加氢脱硫组合技术(简称RCDS技术)。中试结果表明,采用RCDS技术处理具有上述特点的催化裂化汽油生产国Ⅴ标准汽油时的RON损失比单独采用选择性加氢脱硫技术时减少0.9~1.9个单位。工业应用结果表明,采用RCDS技术处理硫质量分数为418~460 μg/g、烯烃体积分数为27.6%~27.9%、芳烃体积分数为19.2%~19.3%的清江石化催化裂化汽油,当产品硫质量分数降低至7 μg/g时,汽油RON损失仅为1.0~1.3个单位,且装置汽油收率高达99.9%。

关键词: 催化裂化汽油, 选择性加氢脱硫, 溶剂抽提, 组合工艺

Abstract: Aiming at the problem of large RON loss in the production of national Ⅴ standard gasoline from the catalytic cracking gasoline feed with high sulfur content,high olefin content and low aromatic content,solvent extraction and selective hydrodesulfurization combined technology(Referred to as RCDS technology) was developed. The results of the pilot test show that the RON loss is reduced by 0.9—1.9 units when using RCDS technology to process the catalytic cracking gasoline with the above characteristics producing national V standard gasoline compared with the selective hydrodesulfurization technology. Industrial application results show that using this technology to process Qingjiang catalytic cracking gasoline with sulfur mass fraction of 418—460 μg/g, olefin volume fraction of 27.6%—27.9%, and aromatic volume fraction of 19.2%—19.3%,When the product sulfur content is reduced to 7 μg/g,the gasoline RON loss is only 1.0—1.3 units,and the gasoline(C5+)yield is as high as 99.9%.

Key words: FCC gasoline, selective hydrodesulfurization, solvent extraction, combination process

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