›› 2019, Vol. 50 ›› Issue (9): 15-20.

• 加工工艺 • 上一篇    下一篇

MHUG-Ⅱ装置国Ⅵ柴油质量升级措施及运转分析

杨文   

  1. 中国石化海南炼油化工有限公司
  • 收稿日期:2019-03-20 修回日期:2019-05-19 出版日期:2019-09-12 发布日期:2019-09-25
  • 通讯作者: 杨文 E-mail:yangw.hnlh@sinopec.com

MEASURES AND OPERATION ANALYSIS OF NATIONAL Ⅵ QUALITY UPGRADING OF DIESEL IN MHUG-II UNIT

Yang Wen   

  • Received:2019-03-20 Revised:2019-05-19 Online:2019-09-12 Published:2019-09-25
  • Contact: Yang Wen E-mail:yangw.hnlh@sinopec.com

摘要: 为了适应生产国Ⅵ柴油及装置长周期运行的需求,中国石化海南炼油化工有限公司(简称海南炼化)对2.48 Mt/a柴油加氢改质MHUG-Ⅱ装置进行了升级再改造,新增一台加氢精制反应器,对第一周期催化剂进行再生,并使用了新型加氢精制催化剂RS-2100及优化了RG系列保护剂的级配。标定结果表明,改造后装置柴油产品的密度(20 ℃)为0.843 4 g/cm3,十六烷值达到51.6,硫质量分数为2.3 μg/g,多环芳烃质量分数为3.4%,总污染物质量分数为5 μg/g,各项指标均满足国Ⅵ车用柴油质量标准。装置于2018年1月23日开工至2019年4月30日灵活性生产国Ⅴ或国Ⅵ标准柴油累计463天,加氢改质反应器中加氢精制催化剂和加氢改质催化剂的平均失活速率分别为0.029 ℃/d和0.015 ℃/d,加氢精制反应器Ⅰ和加氢精制反应器Ⅱ中催化剂的平均失活速率分别为0.027 ℃/d和0.012 ℃/d,由此测算得出各催化剂总运行时间可达到4~5年,与装置检修周期目标一致,可以满足装置质量升级和长周期运行的要求。

关键词: MHUG-Ⅱ装置, 质量升级, 流程改造, 国Ⅵ车用柴油

Abstract: In order to produce national VI diesel and meet the requirement of long-term operation of the unit, SINOPEC Hainan Refining and Chemical Company, Limited. upgraded the 2.48Mt/a diesel hydroupgrading MHUG-II unit, added a new refining reactor, regenerated the first-cycle used catalyst, adopted RS-2100 hydrorefining catalyst, and optimized the gradation of RG series protective catalysts. The calibration results showed that the density of diesel products was 0.843 4 kg/m3, the cetane number was 51.6, the sulfur content was 2.3μg/g, the polycyclic aromatic hydrocarbons content was 3.4% (mass fraction), and the total pollutant content was 5 μg/g, all of which met national VI diesel standards. From January 23, 2018 to April 30, 2019, the unit flexibly produced national V/VI diesel oils for 463 days. The average deactivation rates of refining and hydroupgrading catalysts were 0.029 ℃/d and 0.015 ℃/d, respectively. The average deactivation rates of refining reactor I and II catalysts were 0.027 ℃/d and 0.012 ℃/d, respectively. The total life cycle of each catalyst satisfied with the target of 4-5 years maintenance requirements.

Key words: MHUG-Ⅱunit, quality upgrading, process revamping, national VI diesel