石油炼制与化工 ›› 2019, Vol. 50 ›› Issue (9): 75-80.

• 油品与添加剂 • 上一篇    下一篇

锂基润滑脂的微观结构

栗志彬,康军,吴宝杰   

  1. 中国石化润滑油有限公司天津分公司
  • 收稿日期:2019-02-20 修回日期:2019-04-10 出版日期:2019-09-12 发布日期:2019-09-25
  • 通讯作者: 栗志彬 E-mail:lizb.lube@sinopec.com
  • 基金资助:
     

MICROSTRUCTURE OF LITHIUM GREASE

    

  1.  
  • Received:2019-02-20 Revised:2019-04-10 Online:2019-09-12 Published:2019-09-25
  • Supported by:
     

摘要: 稠化剂是润滑脂的主要组分,其结构与组成决定润滑脂的重要性能。以锂基润滑脂为研究对象,利用MS,XRD,SEM等分析手段,采取结构模拟与试验验证的方法,考察生长与破坏过程中稠化剂纤维的结构变化,目的是研究稠化剂纤维的生长机理。研究结果表明:稠化剂纤维是稠化剂分子的聚集体,其生长过程是稠化剂分子有序排列的结晶过程,稠化剂纤维三维方向的生长情况不同,宽度方向优先生长,长度方向随后生长并引起扭转;其破坏过程与生长过程基本相逆,变化趋势与C模型更为相近。

关键词: 锂基润滑脂, 稠化剂纤维, 微观结构, 结晶过程

Abstract: Thickener is the main component of grease, whose structure and composition determine the important properties of the grease. The structural changes of thickener fiber in lithium grease during growth and destruction were studied by combination of structural simulation and experimental verification methods and MS, XRD, SEM characterization techniques. The results showed that the thickener fiber was the aggregates of thickener molecules, the growth process was a crystallization process in which the molecules of the thickener were arranged in order. The thickener fibers grow differently in three - dimensional direction: the width direction was preferred, and the length direction was followed and twisted. The destruction process of thickener fiber was opposite to its growth basically, which was more similar to the C model.

Key words: lithium grease, thickener fiber, microstructure, crystallization process

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