石油炼制与化工 ›› 2020, Vol. 51 ›› Issue (1): 24-30.

• 催化剂 • 上一篇    下一篇

重整生成油脱烯烃催化剂TORH-1的开发及其应用

臧高山,王涛   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2019-05-16 修回日期:2019-08-28 出版日期:2020-01-12 发布日期:2020-01-19
  • 通讯作者: 臧高山 E-mail:zanggs.ripp@sinopec.com
  • 基金资助:
     

DEVELOPMENT AND APPLICATION OF TORH-1 CATALYST FOR OLEFIN REMOVAL FROM REFORMATE

    

  1.  
  • Received:2019-05-16 Revised:2019-08-28 Online:2020-01-12 Published:2020-01-19
  • Contact: Zang Gaoshan E-mail:zanggs.ripp@sinopec.com
  • Supported by:
     

摘要: 开发了一种用于脱除重整生成油或混合芳烃中烯烃的加氢精制催化剂TORH-1,该催化剂以具有独特孔道结构的新型氧化铝材料为载体,以Pd和Pt为主要活性组分。实验室中型试验、工业侧线试验、工业试验及工业应用结果表明,TORH-1催化剂具有良好的脱烯烃活性、选择性、稳定性以及对复杂原料的适应性,可以完全替代工业颗粒白土。TORH-1催化剂开工不需要额外预硫化,开工方法简便、安全和绿色环保。

关键词: 重整, 生成油, 烯烃, 白土, 分子筛, 加氢催化剂

Abstract: A hydrofining catalyst TORH-1 was developed for removing olefin from reformate or from mixed aromatic hydrocarbons. The catalyst was supported on a new alumina base material with unique pore structure, Pd and Pt were used as main active components. The results of pilot test, industrial side line test and industrial application showed that TORH-1 catalyst had a good deolefin activity, selectivity,stability and adaptability to complex raw materials and could completely replace the industrial clay. TORH-1 catalyst does not need additional presulfidation to start-up and the starting method is simple, safe and green.

Key words: reforming, reformate, olefin, clay, zeolite, hydrogenation catalyst

中图分类号: