石油炼制与化工 ›› 2020, Vol. 51 ›› Issue (10): 32-35.

• 加工工艺 • 上一篇    下一篇

蜡油加氢装置生产国V柴油的工业实践

苏广训,李永超,代磊,贾宝强,王雪平   

  1. 中国石化石家庄炼化分公司
  • 收稿日期:2020-03-30 修回日期:2020-04-29 出版日期:2020-10-12 发布日期:2020-10-27
  • 通讯作者: 苏广训 E-mail:348856359@qq.com

INDUSTRIAL PRACTICE OF VGO HYDROGENATION UNIT TO PRODUCE CHINA Ⅴ DIESEL

  • Received:2020-03-30 Revised:2020-04-29 Online:2020-10-12 Published:2020-10-27

摘要: 为应对柴油液相循环加氢装置停工换剂期间柴油无法出厂的问题,中国石化石家庄炼化分公司进行了采用蜡油加氢装置生产国Ⅴ柴油的工业实践。结果表明,在装置处理量为175 t/h、反应器入口温度为352 ℃、反应压力为9.4 MPa、氢油体积比为500、体积空速为0.97 h-1、分馏塔塔底温度为222 ℃、分馏塔塔顶压力为0.11 MPa的工艺条件下,柴油产品硫质量分数稳定在3 μg/g,达到国Ⅴ柴油标准。在蜡油加氢装置生产国Ⅴ柴油期间发现冷高压分离器超负荷、加热炉超负荷、尾油出装置温度高、柴油水含量高等问题,问题皆得以解决。工业实践的结果可为蜡油加氢装置生产国Ⅴ柴油提供数据支撑及改造依据。

关键词: 蜡油加氢, 国V柴油, 水含量, 硫含量

Abstract: In order to solve the problem that diesel cannotbe sold during shutdown and catalyst replacement of diesel liquid phase circulating hydrogenation unit, SINOPEC Shijiazhuang Refining and Chemical Company produced the China Ⅴ diesel through VGO hydrogenation unit. The results showed that the sulfur content of diesel product was 3 μg/g under the conditions of a capacity of 175 t/h , a reactor inlet temperature of 352 ℃,a reaction pressure of 9.4 MPa, a hydrogen oil volume ratio of 500, a space velocity of 0.97 h-1, a fractionator bottom temperature of 222 ℃ and a top pressure of 0.11 MPa. During the operation, it was found that the cold high pressure separator and the heating furnace were overloaded, the outlet temperature of the tail oil from the unit was on the high side, and the diesel water content was also high. These problems were well resolved. The results of industrial practice can provide data support and basis for transformation of the unit for the production of China Ⅴ diesel fuel.

Key words: VGO hydrogenation, China V diesel, water content, sulfur content