石油炼制与化工 ›› 2020, Vol. 51 ›› Issue (10): 42-45.

• 加工工艺 • 上一篇    下一篇

重整生成油脱氯剂床层压降偏高原因分析及对策

孙黄鹤   

  1. 中国石油广西石化分公司
  • 收稿日期:2020-03-30 修回日期:2020-05-17 出版日期:2020-10-12 发布日期:2020-10-27
  • 通讯作者: 孙黄鹤 E-mail:sunhuanghe@petrochina.com.cn

CAUSE ANALYSIS AND COUNTERMEASURES OF HIGH PRESSURE DROP OF DECHLORINATING AGENT BED FOR REFORMATE

  1. Petrochina Guangxi Petrochemical Company
  • Received:2020-03-30 Revised:2020-05-17 Online:2020-10-12 Published:2020-10-27

摘要: 某炼油厂2.2 Mt/a连续重整装置首次使用分子筛型液相脱氯剂过程中出现了脱氯罐床层压降不断上升的情况,导致下游脱戊烷塔操作困难。经对脱氯剂的废剂分析,发现主要原因是重整生成油中芳烃大分子物质堵塞分子筛微孔所致。采取在脱氯罐床层顶部装填少量大直径、大孔径分子筛脱氯剂作为保护层的措施后,能有效解决脱氯罐床层压降升高问题,同时提出应重视对重整原料终馏点和氮含量的控制的建议。

关键词: 连续重整, 分子筛, 液相脱氯剂, 床层压降

Abstract: During the first application of molecular sieve type liquid phase dechlorination agent in a 2.2 Mt/a continuous reforming unit of a refinery, it was found that the pressure drop of dechlorination agent bed was increasing, which made the operation of downstream depentanizer difficult. The analysis of the waste dechlorination agent indicated that the large molecular aromatics in reformate blocked the micropores of the molecular sieve, leading the pressure drop rising. A small amount of molecular sieve with large diameter and large pores dechlorination agent loaded on the top of the dechlorination bed can effectively solve the problem. At the same time, it is proposed that attention should be paid to the control of the final boiling point and nitrogen content of the reformer feed.

Key words: continuous catalytic reforming, molecular sieve, liquid phase dechlorination agent, bed pressure drop