石油炼制与化工 ›› 2020, Vol. 51 ›› Issue (12): 102-106.

• 分析与评定 • 上一篇    下一篇

闭口闪点测定方法的对比分析

楚卫军,许志国   

  1. 中国人民解放军95958部队
  • 收稿日期:2020-04-23 修回日期:2020-07-22 出版日期:2020-12-12 发布日期:2020-12-29
  • 通讯作者: 楚卫军 E-mail:chuwj1@qq.com
  • 基金资助:
     

COMPARATIVE STUDY ON CLOSED CUP FLASH POINT TEST METHODS

    

  1.  
  • Received:2020-04-23 Revised:2020-07-22 Online:2020-12-12 Published:2020-12-29
  • Supported by:
     

摘要: 对我国常用的闭口闪点测定方法宾斯基-马丁闭口杯法、阿贝尔闭口杯法和泰格闭口杯法的测定原理进行对比分析,并采用这3种方法分别对2种有证标准样品、4种有机试剂样品和7种喷气燃料样品的闭口闪点进行测定。结果表明:这3种方法在适用范围、仪器结构、升温速率和点火操作要求等方面都有一定差异,导致采用这3种方法测定同一样品的闭口闪点结果略有差异,闪点测定结果之间的最大差值与样品闪点的高低呈正相关;与阿贝尔闭口杯法相比,宾斯基-马丁闭口杯法测得的闪点结果较高,对于3号喷气燃料,二者之差为0~1.0 ℃,阿贝尔闭口杯法更适合3号喷气燃料闭口闪点的测定;对于纯有机试剂样品,阿贝尔闭口杯法和宾斯基-马丁闭口杯法测得的闪点结果呈现较好的线性关系。

关键词: 闭口闪点, 宾斯基-马丁闭口杯法, 阿贝尔闭口杯法, 泰格闭口杯法

Abstract: In this study, the commonly used test methods for closed cup flash point measurement,Pensky-Martens closed cup method, Abel closed cup method and Tag closed cup method, were analyzed comparatively. The closed cup flash points of two certified reference material samples, four organic compound samples and seven jet fuel samples were tested by these three methods. It was found that there were some differences of the three methods in application scope, instrument structure, temperature rise speed, ignition operation requirements. As a result, the closed cup flash points of the same sample determined by these three methods were slightly different. The maximum difference among the test results of the same sample by the three methods was positively correlated with its flash point. In general, the flash point determined by Pensky-Martens closed cup method was a little higher than that of Abel closed cup method. For No.3 jet fuel samples, the difference of flash points was 0-1.0 ℃, and in comparison, Abel closed cup method was the most suitable for the determination of closed cup flash point of No.3 jet fuel. For pure organic compound samples, there is a good linear relationship between the results by Pensky-Martens closed cup method and Abel closed cup method.

Key words: closed cup flash point, Pensky-Martens closed cup method, Abel closed cup method, Tag closed cup method

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