石油炼制与化工 ›› 2020, Vol. 51 ›› Issue (12): 85-91.

• 节能减排 • 上一篇    下一篇

基于Tanks 4.0.9d模型的储罐VOCs排放特征定量研究

杨悦1,2,3,徐家洛1,2,3,黄银芝1,2,3,修光利1,2,3   

  1. 1.华东理工大学资源与环境工程学院,上海市环境保护化学污染物环境标准与风险管理重点实验室
    2.国家环境保护化工过程环境风险评价与控制重点实验室
    3.上海污染控制与生态安全研究院
  • 收稿日期:2020-05-28 修回日期:2020-07-11 出版日期:2020-12-12 发布日期:2020-12-29
  • 通讯作者: 修光利 E-mail:xiugl@ecust.edu.cn
  • 基金资助:
    上海市环保科研项目;国家自然科学基金项目

QUANTITATIVE STUDY OF STORAGE TANKS VOCs EMISSION CHARACTERISTICS BASED ON TANKS 4.0.9d MODEL

    

  1.  
  • Received:2020-05-28 Revised:2020-07-11 Online:2020-12-12 Published:2020-12-29
  • Contact: guangli XIU E-mail:xiugl@ecust.edu.cn
  • Supported by:
    Shanghai Environmental Protection Research Project;National Natural Science Foundation of China

摘要: 基于美国EPA发布的Tanks 4.0.9d模型,对储罐VOCs的排放特征及影响因素进行定量研究,并分析与实测数据的差异。研究表明:储罐VOCs排放受结构特征、环境因素及操作条件的影响;内浮顶罐VOCs排放量最小,固定顶罐VOCs排放量是内浮顶罐的110.5倍;对罐外壁修补白色的底漆,定时进行水喷淋或设置隔热挡板,罐内壁使用防锈防腐材料涂层;运用LDAR (泄漏检测与修复)技术对储罐及其配件进行定期定量的泄漏排查并及时修复等方式均是减少储罐VOCs排放的措施。实地监测得到的VOCs排放量高于模型计算结果,内浮顶汽油罐实测数据是模型计算结果的3.5倍,实测与模型计算等核算方法均存在局限性,建议相关部门根据我国的实际情况开发相应的计算软件,对核算公式进行优化。

关键词: 储罐, VOCs排放, Tanks 4.0.9d模型, 排放核算方法

Abstract: Based on the Tanks 4.0.9d model published by US EPA, the paper quantitatively studied the emission characteristics and influence factors on VOCs emission from the storage tank. The difference between the measured data and the model calculation results was analyzed. The results showed that the emissions of storage tanks were affected by tank structural characteristics, environmental factors, and operating conditions. The emission of the internal floating roof tank was the smallest, and the emission of the fixed roof tank was 110.5 times that of the former tank. The reduction of the tank emission could be realized by measures of painting the outer wall of the tank with white primer, regularly spraying water, installing heat insulation baffle, using anti-rust and anti-corrosion coating on the inner wall of the tank, and using LDAR (leak detection and repair) technology to regularly and quantitatively check the leakage of storage tank and repair them in time. It was found that the measured data of internal floating roof gasoline tank was 3.5 times that calculated by the model, showing that the emission from field monitoring was higher than that of calculation by the model. There are limitations in both actual measurement and model calculation. It is suggested that developing new optimized calculation softwares are of great necessity based on the domestic situation.

Key words: storage tank, VOCs emission, Tanks 4.0.9d, emission calculation methods

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