石油炼制与化工 ›› 2020, Vol. 51 ›› Issue (8): 81-86.

• 油品与添加剂 • 上一篇    下一篇

水滑石/废橡胶粉复合改性沥青的制备及其性能研究

鲁玉莹1,余黎明2,杨加可1,曾武松1,陆江银1   

  1. 1. 新疆大学化学化工学院石油天然气精细化工教育部重点实验室
    2. 新疆北新四方工程检测咨询有限公司
  • 收稿日期:2020-02-10 修回日期:2020-03-29 出版日期:2020-08-12 发布日期:2020-08-27
  • 通讯作者: 陆江银 E-mail:jiangyinlu6410@163.com
  • 基金资助:
    双金属/介微孔分子筛加氢裂化催化剂的制备及其催化循环油制备1-2环芳烃反应机理的研究;水滑石/废胶粉复合改性基质沥青的研究

PREPARATION AND PROPERTIES OF ASPHALT MODIFIED BY HYDROTALCITE/WASTE CRUMB RUBBER COMPOSITE

    

  1.  
  • Received:2020-02-10 Revised:2020-03-29 Online:2020-08-12 Published:2020-08-27
  • Contact: Lu Jiangyin E-mail:jiangyinlu6410@163.com
  • Supported by:
     

摘要: 以克拉玛依90号沥青作为基质沥青、废橡胶粉和水滑石(LDHs)作为改性剂,制备了LDHs/废橡胶粉复合改性沥青,在废橡胶粉加入量不变的条件下,考察LDHs加入量对复合改性沥青的物理性能、抗紫外老化性能和流变性能的影响。结果表明:当废橡胶粉加入量(w)为15%时,随着LDHs的加入,复合改性沥青的软化点升高,针入度和延度有所下降,两种改性剂相互结合,使复合改性沥青的物理性能得到改善,并且满足国家聚合物改性沥青标准的要求,考虑到改性剂成本,选取LDHs加入量(w)为3%~4%;LDHs的加入使复合改性沥青的软化点增量减小,残留针入度比和延度保留率上升,表明LDHs可明显提高复合改性沥青的抗紫外老化性能;LDHs的加入可使复合改性沥青复数模量和车辙因子增加,相位角下降,说明LDHs可提高复合改性沥青的抗车辙性能。

关键词: 废胶粉, 水滑石, 复合改性沥青, 抗老化

Abstract: Using Karamay No.90 asphalt as a matrix, the modified asphalts by hydrotalcite(LDHs)and waste crumb rubber composite were prepared. The effects of the amount of LDHs on the physical properties, anti-ultraviolet aging performance and rheological properties of the composite modified asphalt were investigated at constant waste crumb rubber amount. The results showed that when the content of waste crumb rubber was 15%, as the addition of LDHs increases, the softening point increased while the penetration and ductility of the composite modified asphalt decreased. It is demonstrated that the integration of two kinds of modifiers improves the physical properties of the composite modified asphalt, and met the requirements of national standard of polymer modified asphalt. Considering the cost of modifying agent, the mass fraction of LDHs added was 3%-4%. The addition of LDHs reduced the softening point increment and increased the residual penetration ratio and ductility retention of the composite modified asphalt, indicating that LDHs can significantly improve the UV aging resistance of the composite modified asphalt. The addition of LDHs can also increase the complex modulus and rutting factor of composite modified asphalt and decrease the phase angle, indicating that LDHs can improve the rutting resistance of composite modified asphalt.

Key words: rubber power, LDHs, composite modified asphalt, anti-aging

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