石油炼制与化工 ›› 2021, Vol. 52 ›› Issue (10): 10-17.

• 特约综述 • 上一篇    下一篇

重质油制烯烃的催化裂化家族工艺开发回顾及展望

朱根权,汪燮卿   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2021-06-14 出版日期:2021-10-12 发布日期:2021-09-29
  • 通讯作者: 汪燮卿 E-mail:wangxieqing.ripp@sinoepc.com

REVIEW AND FORECAST ON DEVELOPMENT OF LIGHT OLEFINS PRODUCTION WITH HEAVY FEEDSTOCKS VIA FCC FAMILY PROCESSES

Zhu Genquan,Wang Xieqing   

  • Received:2021-06-14 Online:2021-10-12 Published:2021-09-29
  • Contact: Wang Xieqing E-mail:wangxieqing.ripp@sinoepc.com

摘要: 回顾了中国石化石油化工科学研究院开发的重质原料制轻烯烃的催化裂化家族工艺的发展过程。这些技术与催化裂化工艺的不同在于其采用了新的工艺设备布置和特殊配方催化剂。催化裂化家族工艺主要包括以重质油为原料多产丙烯的催化裂解(DCC-I)技术、多产丙烯兼顾生产优质汽油的催化裂解(DCC-Ⅱ)技术,最大量生产优质汽油和液化气(MGG)技术、用常压渣油最大量生产优质汽油和液化气(ARGG)技术,提高柴油并多产气体烯烃和液化气(MGD)技术,重油催化裂化提高异构C4和C5气体烯烃产率(MIO)技术,以重质油为原料最大量生产乙烯和丙烯的催化热裂解(CPP)技术,选择性催化裂解(MCP)技术、增强型催化裂解(DCC-plus)技术、高效催化裂解(RTC)技术。介绍了这些技术开发及工业应用的过程及结果,展望了其未来发展方向,为炼油向化工转型提供参考。

关键词: 重质油, 催化裂化, 乙烯, 丙烯, 液化气, 汽油, 柴油

Abstract: The development history of a series of processes for producing of light olefins on the basis of heavy oil as feed and extended technology of FCC developed by SINOPEC Research Institute of Petroleum Processing are reviewed. The differences between these processes to FCC lie on the new configuration of process equipment and specially formulated catalyst. The major processes include as follows: Deep Catalytic Cracking (DCC) for propylene production intentionally, Catalytic Pyrolysis Process (CPP) for ethylene and propylene on purpose, Maximizing Gaseous olefins and Gasoline(MGG) for high yield of value-added products, Atmospheric Residue for Gaseous olefin and Gasoline(ARGG) for heavier paraffinic feed, Maximizing Gaseous olefins and Diesel fuel (MGD) for occasional fuel market change for more diesel, and Maximizing Iso-Olefins (MIO)for chemicals, Maximizing Catalytic Propylene (MCP) technology by selective catalytic cracking, Enhanced DCC (DCC plus) technology, and novel deep catalytic cracking technology for Resid to Chemicals(RTC). The progress of the development and industrial application of these processes are introduced and forecasted, which can provide a reference for the transformation from oil refining to chemical industry.

Key words: heavy oil, catalytic cracking, ethylene, propylene, Liquefied petroleum gas, gasoline, diesel