石油炼制与化工 ›› 2021, Vol. 52 ›› Issue (10): 110-117.

• 特约研究报告 • 上一篇    下一篇

炼油结构转型下沸腾床加氢技术

仝玉军,杨涛,方向晨,侯栓弟   

  1. 中国石化大连石油化工研究院
  • 收稿日期:2021-08-13 修回日期:2021-06-17 出版日期:2021-10-12 发布日期:2021-09-29
  • 通讯作者: 仝玉军 E-mail:tongyujun.fshy@sinopec.com

DEVELOPMENT OF EBULLATED BED HYDROGENATION TECHNOLOGY UNDER STRUCTURE TRANSFORMATION OF OIL REFINING

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  • Received:2021-08-13 Revised:2021-06-17 Online:2021-10-12 Published:2021-09-29
  • Contact: yujun tong E-mail:tongyujun.fshy@sinopec.com

摘要: STRONG技术是中国石油化工股份有限公司自主开发的沸腾床加氢技术,其创造性提出了气-液-固自分离的三相分离器替代高温高压沸腾泵,实现了气-液-固高效分离和自持流化;创制的适宜不同反应分区的球形催化剂,具有良好流化性能和较高的杂质脱除率,实现了劣质渣油的高效提质和产物分布的灵活调变,而且适应不同原料加工场景(如渣油、煤焦油等)和目标产物(如清洁油品、化工原料、低硫船用燃料油和低硫石油焦等)。目前已建成50 kt/a示范装置和500 kt/a工业装置,并完成百万吨规模的工艺包编制工作。为应对炼油结构转型,在STRONG沸腾床加氢技术基础上,开发出沸腾床-固定床复合床(SiRUT)技术,该新技术具有原料适应性强、装置运行周期长和加氢重油性质显著提升等优点,在现有及未来炼油企业提质增效方面具有竞争优势。

关键词: 炼油结构转型, STRONG沸腾床加氢, 固定床加氢, 复合床技术

Abstract: The characteristics of STRONG ebullated bed hydrogenation technology independently developed by SINOPEC was described and the newly developed SINOPEC integrated resid upgrading technology (SiRUT) was introduced. Compared with other ebullated bed hydrogenation technology, the expensive high temperature and high pressure circulating pump was canceled in STRONG ebullated bed technology, and high-efficiency separation of gas-liquid-solid and self-sustaining fluidization were implemented. The new spherical catalyst, suitable for different reaction zones, good fluidization performance and high impurity removal rate, was developed. Moreover, the STRONG ebullated bed technology had characteristics of high-efficiency upgrading of inferior residue, flexible adjustment of product distribution and adaption to different raw material processing scenarios (such as residual oil, coal tar, etc.) and target products (such as clean oil, chemical raw materials, low-sulfur ship fuel, low-sulfur petroleum coke, etc.). At present, 50,000-ton/year demonstration device and 500,000-ton/year industrial ebullated bed device had been built, and the preparation of a million-ton-scale process package had been completed. In response to the structural transformation of oil refining, the SiRUT technology was developed, which had the advantages of strong raw material adaptability, long operation cycle of the device, and significantly improved properties of hydrogenated heavy oil. This new technology had high competitive advantage in improving quality and efficiency of existing and future refineries.

Key words: oil refining transformation, STRONG ebullated bed hydrogenation, fixed bed hydrogenation, SiRUT