石油炼制与化工 ›› 2021, Vol. 52 ›› Issue (6): 57-63.

• 加工工艺 • 上一篇    下一篇

4.0 Mt/a蜡油加氢裂化装置的运行优化

郭振刚   

  1. 浙江石油化工有限公司
  • 收稿日期:2020-11-02 修回日期:2020-12-01 出版日期:2021-06-12 发布日期:2021-06-01
  • 通讯作者: 郭振刚 E-mail:zsh_guozg@rong-sheng.com

OPERATION OPTIMIZATION OF A 4.0 Mt/a VGO HYDROCRACKING UNIT

  1. Zhejiang Petrochemical Co., Ltd
  • Received:2020-11-02 Revised:2020-12-01 Online:2021-06-12 Published:2021-06-01

摘要: 浙江石油化工有限公司4.0 Mt/a蜡油加氢裂化装置采用UOP公司的UnicrackingTM加氢裂化技术,级配装填加氢精制剂HYT-6219与加氢裂化剂HC-185LT,装置开工后一直维持95%以上负荷稳定运行。通过对装置运行优化研究及总结,拓宽加工原料范围,掺炼催化裂化柴油和焦化柴油总量平均为57t/h,掺炼催化裂化柴油和焦化柴油期间各产品质量合格,重石脑油+喷气燃料+柴油的收率增加5.17百分点;优化原料组成、改变裂化反应深度和调整分馏切割操作,柴油侧线生产出运动黏度(40 ℃)为4.345mm2/s、闪点(开口)为126℃的5号工业白油(Ⅰ)产品;优化分馏操作,喷气燃料收率由20.7%增加至26.6%,产量较设计值增加35.5t/h;脱异戊烷单元生产出异戊烷质量分数达99.20%、总的戊烷质量分数为99.66%的F0型戊烷发泡剂。通过一系列的优化运行,提高了装置产品附加值及高质产品收率,装置运行整体经济性明显提高,发挥了蜡油加氢裂化装置在炼化一体化项目中产品结构调整灵活的优势。

关键词: 加氢裂化, 催化裂化柴油, 焦化柴油, 工业白油, 喷气燃料, 戊烷发泡剂

Abstract: The 4.0 Mt/a VGO hydrocracking unit of Zhejiang Petrochemical Company adopted UOP’s UnicrackingTM hydrocracking technology with the graded catalysts of the hydrotreating catalysts HYT-6219 and hydrocracking catalyst HC-185LT. Since the start-up, the unit has been running stably at over 95% of the load. Based on the research and summary of the unit operation optimization, the average amount of 57 t/h of RFCC diesel and coker diesel was blended as feed, and all the products were qualified, the yield of (heavy naphtha + jet fuel + diesel)was increased by 5.17 percentage points.The No. 5 industrial white oil (I) with kinematic viscosity of 4.345 mm2/s and flash point (open cup) of 126℃ was produced from the diesel side line of fractionator.The yield of jet fuel was increased from 20.7% to 26.6%, and the production was increased by 35.5 t/h compared with the design.The F0 pentane foaming agent with isopentane content of 99.20%andtotal pentane content of 99.66% was produced on deisopentanizer.Through a series of optimized operation, the value added product and the output of the unit were improved, and the overall operation economy of the unit was significantly increased.The advantages of flexible product structure adjustment of VGO hydrocracking unit in refining and chemical integration project were achieved.

Key words: Hydrocracking, RFCC diesel, coker diesel, Industrial white oil, Jet fuel, pentane foaming agent