石油炼制与化工 ›› 2021, Vol. 52 ›› Issue (8): 102-107.

• 节能减排 • 上一篇    下一篇

Y分子筛含硅母液和滤液绿色回用工程技术开发

伍欣华,陈媛媛,单高峰,谢庚华   

  1. 中国石化催化剂有限公司长岭分公司
  • 收稿日期:2021-03-23 修回日期:2021-04-30 出版日期:2021-08-12 发布日期:2021-07-29
  • 通讯作者: 伍欣华 E-mail:wuxinhua.chji@sinopec.com

DEVELOPMENT OF GREEN REUSE ENGINEERING TECHNOLOGY FOR MOTHER LIQUOR AND FILTRATE CONTAINING SILICON IN PRODUCTION OF Y MOLECULAR SIEVE

  • Received:2021-03-23 Revised:2021-04-30 Online:2021-08-12 Published:2021-07-29

摘要: 对现有NaY分子筛含硅母液和滤液的组成、体积、固体颗粒物性质进行分析,确定了含硅母液和滤液的固-液快速分离技术,去除NaY微晶和P型杂晶,以提高硅的回用比例;确定了含硅母液及滤液等比例在线混合全回用技术,进一步提高了硅的利用率。通过两项技术的工业化,在保证NaY分子筛性质的前提下,硅利用率提高至92.85%,既降低了生产成本,又缓解了因分子筛含硅废液排放造成的环境污染问题。

关键词: NaY分子筛, 含硅母液和滤液, NaY微晶, P型杂晶, 全回用, 合成

Abstract: The composition, volume and properties of solid particles of the existing mother liquid and filtrate containing silicon in the production of NaY molecular sieve were analyzed. A rapid solid-liquid separation technology was developed to remove NaY microcrystals and P-type heterocrystals, so as to improve the proportion of silicon reuse. In order to further improve the utilization rate of silicon, the online mixing and full reuse technology of mother liquor and filtrate containing silicon was determined. Through the industrialization of the two technologies, on the premise of ensuring the inner property of NaY molecular sieve, the annual silicon utilization rate was increased to 92.85%, which not only reduced the production cost, but also alleviated the environmental pollution caused by the discharge of silicon waste liquid of molecular sieve.

Key words: NaY molecular sieve, mother liquor and filtrate containing silicon, NaY microcrystal, P-type heterocrystals, total reuse, synthesis