添加剂对含生物柴油的发动机油抗氧化性能的影响

石油炼制与化工 ›› 2021, Vol. 52 ›› Issue (8): 90-95.

添加剂对含生物柴油的发动机油抗氧化性能的影响

邵腾飞,包冬梅,杨超

中国石油大连润滑油研究开发中心

收稿日期:2020-12-23 修回日期:2021-03-17 出版日期:2021-08-12 发布日期:2021-07-29
通讯作者: 邵腾飞 E-mail:shaotengfei_rhy@petrochina.com.cn

INFLUENCE OF ADDITIVES ON ANTI-OXIDATION PERFORMANCE OF ENGINE OILS BLENDED WITH BIODIESEL

Received:2020-12-23 Revised:2021-03-17 Online:2021-08-12 Published:2021-07-29

摘要/Abstract

摘要： 参照GFC Lu-43-A-11方法，在ACEA C3 5W-30规格配方油品的基础上，研究了发动机油在含生物柴油条件下的抗氧化性能，系统考察了在生物柴油存在条件下润滑油抗氧剂、抗氧抗腐剂（ZDDP）、清净剂、分散剂等添加剂对发动机油抗氧化性能的影响。结果表明：在含生物柴油条件下，胺型抗氧剂、仲烷基ZDDP、高碱值清净剂、高分子丁二酰亚胺分散剂等添加剂对抑制发动机油的氧化衰变过程具有更好的效果。

关键词: 发动机油, 生物柴油, 氧化性能, 添加剂

Abstract: The simulated oxidation test method of engine oils blended with biodiesel was established referring to GFC Lu-43-A-11. Based on the oil formulation that fits the ACEA C3 5W-30 oil sequence, the influence of additives such as antioxidants, ZDDPs, detergents and dispersants, on anti-oxidation performance of engine oils containing biodiesel was studied. The results demonstrated that the additives such as amine antioxidants, secondary alkyl ZDDPs, high TBN detergents, high molecular weight succinimide dispersants showed better anti-oxidation performance of engine oils containing biodiesel.

Key words: engine oil, biodiesel, oxidation performance, additives

邵腾飞包冬梅杨超. 添加剂对含生物柴油的发动机油抗氧化性能的影响[J]. 石油炼制与化工, 2021, 52(8): 90-95.

参考文献

[1] 魏宇峰，费旭东.我国生物柴油最新版质量标准及检验监督情况综述[J].广东化工, 2015, 42(3):77-80 [2] 董海，仇玄，尹杰.我国生物柴油市场及展望[J].国际石油经济, 2014, (10):94-96 [3] 宋锦玉，宋官龙，史春薇等.欧洲生物柴油燃料及其原料的最新动向[J].应用化工, 2015, 44(8):1515-1519 [4] M Andreae, H Fang and K Bhandary.Biodiesel and Fuel Dilution of Engine Oil[R]. SAE Technical Paper，2007-01-4036. [5] Watson SAG, Wong VW.The effects of fuel dilution with biodiesel and low sulfur diesel on lubricant acidity, oxidation and corrosion: A bench scale study with CJ-4 and CI-4+ lubricants. [C]. STLE/A SME 2008 International Joint Tribology Conference. American Society of Mechanical Engineers，2008：233-235. [6] Anja Singer, Wolfgang Ruck, Juergen Krahl.Influence of Different Biogenic Fuels on Base Oil Aging[R]. SAE Technical Paper, 2014-01-2788. [7]吴江，陈波水，方建华等.生物柴油发动机润滑油氧化衰变特性模拟研究[J].车用发动机, 2008, 31(6):85-88 [8]吴江，陈波水，方建华等.生物柴油对柴油机油氧化、清净和抗磨性能的影响[J].石油学报石油加工, 2009, 25(S1):62-66 [9] Kotaro Mori, Naoya Sugimoto, Koji Yamane, Kiyoshi Kawasaki.Influence of Biodiesel Fuel on Lubricant Oil Oxidative Degradation[R]. SAE Technical Paper, 2015-01-2030. [10]张辉.润滑油抗氧剂的现状与发展趋势[J].石油商技, 2008, 26(6):44-47 [11]王丽娟，刘纬民.润滑油抗氧剂的作用机理[J].润滑油, 1998, 13(2):55-58 [12]薛卫国，杨蕾，伏喜胜等.润滑油抗氧剂的作用机理[J].合成润滑材料, 2015, 42(2):40-46 [13] 黄文轩.抗氧防腐剂的发展应用现状及趋势[J].石油商技, 2016, (4):88-96 [14] 黄文轩.润滑油清净剂的作用机理、主要品种及性能[J].石油商技, 2016, (1):88-95 [15] 黄文轩.润滑油分散剂的品种和性能[J].石油商技, 2016, (2):90-96