石油炼制与化工 ›› 2022, Vol. 53 ›› Issue (10): 66-69.

• 节能减排 • 上一篇    下一篇

环保型低磷循环水处理技术及其应用

王金华1,孙飞1,傅晓萍1,梁世健2   

  1. 1. 中国石化石油化工科学研究院
    2. 中国石化茂名分公司
  • 收稿日期:2022-02-28 修回日期:2022-06-27 出版日期:2022-10-12 发布日期:2022-09-23
  • 通讯作者: 王金华 E-mail:wangjinh.ripp@sinopec.com

RESEARCH AND APPLICATION OF ENVIRONMENTAL FRIENDLY LOW-PHOSPHORUS TREATMENT TECHNOLOGY FOR CIRCULATING WATER

  • Received:2022-02-28 Revised:2022-06-27 Online:2022-10-12 Published:2022-09-23

摘要: 针对新水和回用水水质特点及炼油装置循环水系统工况条件,开发了环保型低磷循环水处理技术。在炼油装置循环水系统进行了3个月的工业试验,碳钢监测试管的平均腐蚀速率为0.032 1 mm/a,平均黏附速率为4.1875 mg/(cm2.月)(1月以30 d计),循环水处理效果良好;回用水占比提升至77.23%,循环水外排总磷质量浓度降幅为70%,具有较好的经济效益和显著的社会效益。

关键词: 污水回用, 低磷水处理剂, 腐蚀, 结垢

Abstract: According to the characteristics of the fresh water and the reused wastewater as well as the working conditions of circulating water system, an environmental friendly low-phosphorus treatment technology was developed. The technology was applied in the circulating water system of the refinery units for three months as the industrial experiments. The results showed that the average corrosion rate and the average adhesion rate of carbon steel test tube were 0.032 1 mm/a and 4.187 5 mg/(cm2.month), respectively. The proportion of the reused wastewater in all make-up water was promoted to 77.23%. The mass concentration of phosphorus introduced by the water treatment agents was decreased by 70%. This treatment technology has shown remarkable economic and social benefits.

Key words: wastewater recycling, low phosphorus water treatment agent, corrosion, scale