石油炼制与化工 ›› 2023, Vol. 54 ›› Issue (12): 114-118.

• 设备及防腐 • 上一篇    下一篇

基于挂片法的铝溶胶腐蚀性能研究

秦鹏飞,周含,徐冬翔,孙敏,刘新   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2023-03-31 修回日期:2023-08-09 出版日期:2023-12-12 发布日期:2023-12-05
  • 通讯作者: 周含 E-mail:zhouh.ripp@sinopec.com

STUDY ON CORROSION PROPERTIES OF ALUMINIUM SOL BASED ON WEIGHT LOSS METHOD

  • Received:2023-03-31 Revised:2023-08-09 Online:2023-12-12 Published:2023-12-05
  • Contact: Han ZHOU E-mail:zhouh.ripp@sinopec.com

摘要: 在催化裂化、甲醇制烯烃等催化剂的制备过程中,作为黏结剂的铝溶胶溶液会对设备造成腐蚀,因此有必要对铝溶胶的性能及其对工业装置的腐蚀速率进行测定。而目前市售的腐蚀性能评价仪存在转速失真、温度延迟不准确、空泡效应等问题,从而影响试验数据的准确性。本研究基于挂片法开发了一套新型四通道高效铝溶胶腐蚀性能评价仪,该仪器采用泵循环铝溶胶液体与原位加热控温相结合的方式,确保了测试体系内无显著温度梯度,优选了铝溶胶对20号碳钢挂片的腐蚀强化条件,最大相对误差仅2.3%,数据重复性良好。采用计算流体力学数值模拟方法研究了铝溶胶速度梯度对挂片腐蚀速率的影响,建立了预测腐蚀速率的计算式,为工业装置腐蚀防护提供了试验数据与模型支持。

关键词: 铝溶胶, 腐蚀性能, 评价, 计算流体力学, 数值模拟

Abstract: During the preparation of catalysts for catalytic cracking, methanol-to-olefin,etc.,aluminum sol solution as a binder will cause corrosion to equipment, so it is necessary to measure the performance of aluminum sol and its corrosion rate to industrial equipment. At present, there are some problems in the commercial corrosion performance evaluation instrument, such as speed distortion, temperature delay inaccuracy, cavitation effect affecting the experimental data and so on, which affect the accuracy of the test data. In order to solve the problems faced by the industry, a new type of four-channel high efficiency alumina sol corrosion evaluation instrument was developed based on weight loss method, and some key technologies such as pumping aluminum sol liquid, in-situ heating and temperature control were used to ensure that there was no significant temperature gradient in the test system. The test results showed that the maximum relative error of corrosion rate of 20# carbon steel coupons in optimum?condition from the apparatus was only 2.3%, and repeatability was good. The effects of velocity gradient on corrosion efficiency of aluminum sol were investigated by CFD numerical simulation. A formula which could predict the corrosion rate was established, which provided the test data and model support for the corrosion protection of industrial equipment.

Key words: aluminum sol, corrosion property, evaluation, computational fluid dynamics, numerical simulation