1,2-丙二醇合成技术进展

摘要/Abstract

摘要： 介绍并对比了环氧丙烷水合法、酯交换法、甘油氢解法和丙烯双氧水法合成1,2-丙二醇技术，其中丙烯双氧水法的原料廉价易得，两步反应集成在一个反应器中进行，1,2-丙二醇收率高，不需要投资环氧丙烷产能，技术经济性好，可以实现1,2-丙二醇的清洁化生产，具有良好的工业化应用前景，建议将开发稳定、高效的非均相催化氧化催化剂作为该技术未来的重点研发方向。

关键词: 丙烯, 双氧水, 催化氧化, 1,2-丙二醇

Abstract: The synthesis of 1,2-propanediol by hydration of propylene oxide, transesterification, hydrogenolysis of glycerol, and reaction of propylene hydrogen with peroxide were introduced and compared. Propylene catalytic oxidation technology has the characteristics of low cost and easy availability of raw materials, integration of two reactions in one reactor, higher yield of 1,2-propanediol, no need to invest in propylene oxide production capacity, and good technical and economic efficiency, which can realize the cleaner production of 1,2-propanediol, and has a good prospect of industrial application. It was suggested that the development of stable and efficient catalytic oxidation catalyst should be the key research direction of this technology in the future.

Key words: propylene, hydrogen peroxide, catalytic oxidation, 1,2-propanediol

马东强彭欣欣罗一斌. 1,2-丙二醇合成技术进展[J]. 石油炼制与化工, 2023, 54(12): 143-148.

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