石油炼制与化工 ›› 2023, Vol. 54 ›› Issue (2): 126-133.

• 综述 • 上一篇    下一篇

ZSM-5催化异丁烯胺化制叔丁胺的研究进展

赵新来1,周广林2,吴谦2,郭修程2   

  1. 1. 淄博鲁华泓锦新材料集团股份有限公司
    2. 中国石油大学(北京)
  • 收稿日期:2022-08-25 修回日期:2022-10-12 出版日期:2023-02-12 发布日期:2023-02-24
  • 通讯作者: 赵新来 E-mail:PeterZhaoXL@luhuachem.com
  • 作者简介:2022-09-22

RESEARCH PROGRESS IN THE SYNTHESIS OF TERT-BUTYLAMINE FROM ISOBUTYLENE AMINATION CATALYZED BY ZSM-5


  • Received:2022-08-25 Revised:2022-10-12 Online:2023-02-12 Published:2023-02-24

摘要: 综述了近年来异丁烯胺化制叔丁胺研究取得的进展,重点从ZSM-5分子筛催化剂的反应过程、改性、活性影响等方面介绍了异丁烯胺化制叔丁胺催化剂的研究进展,总结并展望了异丁烯胺化制叔丁胺的研究方向,为ZSM-5分子筛催化剂的优化和异丁烯胺化制叔丁胺工艺开发提供参考。

关键词: 异丁烯, ZSM-5, 直接胺化, 叔丁胺

Abstract: The progress in the synthesis of tert-butylamine from isobutene in recent years was reviewed, and the research progress of the catalysts for the synthesis of tert-butylamine from isobutene catalyzed by ZSM-5 molecular sieve was mainly introduced from the aspects of the reaction process, modification and activity influence of ZSM-5 molecular sieve catalyst. The research direction of isobutene amination to tert-butylamine was summarized and prospected, which provided a reference for the optimization of ZSM-5 molecular sieve catalyst and the process development of isobutyl amination to tert-butylamine.

Key words: isobutene, ZSM-5, direct amination, tert-butylamine