石油炼制与化工 ›› 2023, Vol. 54 ›› Issue (3): 29-33.

• 加工工艺 • 上一篇    下一篇

3 Mt/a柴油加氢装置改造及应用效果

熊伟庭   

  1. 中国石化茂名分公司
  • 收稿日期:2022-08-25 修回日期:2022-10-28 出版日期:2023-03-12 发布日期:2023-03-23
  • 通讯作者: 熊伟庭 E-mail:xiongwt.mmsh@sinopec.com

MODIFICATION AND APPLICATION EFFECT OF 3 Mt/a DIESEL HYDROGENATION UNIT

Xiong Weiting   

  • Received:2022-08-25 Revised:2022-10-28 Online:2023-03-12 Published:2023-03-23
  • Contact: Xiong Weiting E-mail:xiongwt.mmsh@sinopec.com

摘要: 为高比例掺炼催化裂化柴油,提高全厂柴油质量,中国石化茂名分公司对4号柴油加氢装置进行了技术改造,并对改造后的装置进行了标定。结果表明:通过实施新增改质反应器、调整催化剂级配方式、改造分馏塔塔盘数、增设轻柴油侧线汽提塔等措施,改造后装置在催化裂化柴油掺炼质量比为26.5%、精制反应器入口压力为8.55 MPa、精制反应器入口温度为312.5 ℃、改质反应器入口温度为358.0 ℃的条件下,生产出硫质量分数小于10 μg/g、多环芳烃质量分数小于7%的精制柴油, 其十六烷指数为49.1,比原料油提升5.7,装置能耗为293.52 MJ/t,明显优于装置设计能耗。此外,改造装置运行过程中仍存在一些问题,需要进一步优化装置原料组成,降低原料切换频次。

关键词: 催化裂化, 柴油, 加氢, 十六烷值

Abstract: In order to improve the quality of the diesel in the whole plant and co-processing the high proportion of FCC light cycle oil, SINOPEC Maoming Comany retrofitted the No. 4 diesel hydrogenation unit to carry out the technical transformation calibration. The calibration results showed that the new upgrading reactor, adjustment of the catalyst gradation, modification of fractionation column tray number, and the addition of new light diesel side-line stripper were adopted, the revamped unit was operated under the conditions of diesel blending ratio of 26.5%, inlet pressure of refined reactor of 8.55 MPa, inlet temperature of the refining reaction of 312.5 ℃ and inlet temperature of upgrading reactor of 358.0 ℃ , the cetane index was 49.1, which was 5.7 higher than that of the feedstock, and the energy consumption was 293.52 MJ/t, which was obviously superior to the design energy consumption of the unit. The quality of the refined diesel with sulfur content of less than 10 μg/g and polycyclic aromatic hydrocarbon content of less than 7% could be obtained. At the same time, there were still some the problems in the operation of the unit, which need to further optimize the raw material composition of the unit and reduce the frequency of raw material switching.

Key words: catalytic cracking, light cycle oil, hydrogenation, cetane number