石油炼制与化工 ›› 2023, Vol. 54 ›› Issue (5): 97-100.

• 节能减排 • 上一篇    下一篇

提高液化气脱硫醇过程碱液利用率实现碱渣零排放

张春生   

  1. 中国石化金陵分公司
  • 收稿日期:2022-12-30 修回日期:2022-12-08 出版日期:2023-05-12 发布日期:2023-05-12
  • 通讯作者: 张春生 E-mail:zhangcs.jlsh@sinopec.com

IMPROVING CAUSTIC SOLUTION UTILIZATION IN LPG SWEETENING PROCESS TO REALIZE ZERO DISCHARGE OF SPENT CAUSTICS

  • Received:2022-12-30 Revised:2022-12-08 Online:2023-05-12 Published:2023-05-12

摘要: 通过对液化气脱硫醇精制系统存在的碱液消耗高、碱渣排放量大等问题进行分析,改进各液化气脱硫醇单元碱洗流程,新增碱渣再生装置,各装置的精制液化气硫质量浓度不大于20 mg/m3,产品质量明显提高,新鲜碱消耗量和碱渣排放量大幅降低。利旧纤维膜碱渣CO2中和装置,碱渣湿式氧化单元可以停用,实现了碱渣零排放。

关键词: 液化气, 脱硫醇, 碱液, 碱渣, 零排放

Abstract: By analyzing the problems of high caustic consumption and large spent caustics discharge in the treating system of LPG sweetening process, the caustic scrubbing process of each LPG sweetening unit was improved and a spent caustics regeneration unit was added, and the total sulfur concentration of refined LPG in each unit is not more than 20 mg/m3, the product quality is significantly improved, and the consumption of fresh caustic solution and the discharge of caustic residue are significantly reduced. Through utilizing the old fiber membrane caustics CO2 neutralization device, the caustics wet oxidation unit can be stopped, realizing zero discharge of caustics.

Key words: liquid gas, sweetening, caustic solution, spent caustics, zero discharge