石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (5): 14-19.

• 加工工艺 • 上一篇    下一篇

芳烃抽提蒸馏工艺(SED-BTX)的开发与应用

赵明1,蹇忠立2,田龙胜1,唐文成1   

  1. 1. 中石化石油化工科学研究院有限公司
    2. 中化泉州石化有限公司
  • 收稿日期:2023-09-07 修回日期:2024-01-29 出版日期:2024-05-12 发布日期:2024-05-06
  • 通讯作者: 田龙胜 E-mail:tianls.ripp@sinopec.com

DEVELOPMENT AND APPLICATION OF AROMATICSEXTRACTION AND DISTILLATION PROCESS (SED-BTX)

  • Received:2023-09-07 Revised:2024-01-29 Online:2024-05-12 Published:2024-05-06
  • Contact: Tian Longsheng E-mail:tianls.ripp@sinopec.com

摘要: 通过建立完善的相平衡数据包及过程模拟系统,开发了以加氢处理后的催化裂解汽油为原料的芳烃抽提蒸馏(SED-BTX)新工艺。该工艺以抽提蒸馏为核心,将抽提蒸馏与液液抽提进行有机组合,利用各自的优势,既节能降碳,又实现轻质芳烃(BTX)产品高回收率、高纯度的目的。SED-BTX工艺在350 kt/a工业装置上应用一次开车成功,结果表明:苯产品收率达到99.9%,纯度(w)达到99.99%;甲苯产品收率达到99.9%,纯度达到99.98%;抽余油中非芳烃质量分数大于99.3%,环丁砜质量分数小于1 μg/g;包括精馏部分在内的全装置综合能耗为56.6 kgOE/t(1 kgOE=41.8 MJ),相比传统的液液抽提工艺降低25%。

关键词: 催化裂解汽油, 芳烃, 抽提蒸馏

Abstract: A new process for aromatics extraction and distillation (SED-BTX) of hydrogenated catalytic cracking gasoline was developedby establishing a comprehensive phase equilibrium data package and process simulation system. This process takes extraction distillation as the core, combines extraction distillation and liquid-liquid extraction organically, and makes use of their respective advantages to achieve the goals of energy conservation and carbon reduction, as well as high recovery rate and high purity of BTX products. The SED-BTX process was successfully applied to a 350 kt/a industrial plant in one run. The results showed that the yield and purity of benzene product reached 99.9% and 99.99% respectively, that of toluene product reached 99.9% and 99.98% respectively,the non-aromatic content in the raffinate oil was over 99.3%, and the sulfolane content was less than 1 μg/g. The comprehensive energy consumption of the whole unit including the distillation unit was 56.6 kgOE/t(1 kgOE=41.8 MJ), which was 25% lower than the traditional liquid-liquid extraction process.

Key words: catalytic cracking gasoline, aromatics, extraction and distillation