石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (6): 148-153.

• 油品与添加剂 • 上一篇    下一篇

环状二元酸单酯抗磨剂的合成及性能研究

杨修政1,夏鑫1,黄娜岚1,蔺建民1,李妍1,杨鹤1,尚小龙2   

  1. 1. 中石化石油化工科学研究院有限公司
    2. 北京兴普精细化工技术开发公司
  • 收稿日期:2023-11-15 修回日期:2024-02-13 出版日期:2024-06-12 发布日期:2024-05-28
  • 通讯作者: 蔺建民 E-mail:linjm.ripp@sinopec.com
  • 基金资助:
    中石化股份公司项目

SYNTHESIS AND PERFORMANCE RESEARCH OF CYCLIC DICARBOXYLIC ACID MONOESTER ANTI-WEAR AGENT

  • Received:2023-11-15 Revised:2024-02-13 Online:2024-06-12 Published:2024-05-28
  • Contact: Jianmin JianminLin E-mail:linjm.ripp@sinopec.com

摘要: 由于环状结构物质的环状张力,使其低温性能较长链烷烃更优异。以多种环状酸酐与醇(醚)为原料,经酯化反应合成系列单酯化产物,并分别对其抗磨效果和低温性能进行分析。结果表明:在所研究的多种环状二元酸单酯产物中,甲基六氢邻苯二甲酸酐与乙二醇单丁醚(2-B)反应制备的甲基六氢邻苯二甲酸单乙二醇丁醚酯兼具良好的抗磨性能和低温性能,在超低硫柴油中的加剂量仅为200 μg/g时就能显著提高柴油的润滑性能,平均磨斑直径减小242μm,且平均摩擦因数降低51%,平均油膜覆盖率提高10%;2-BM的凝点为﹣42℃,在低温环境条件下具备一定的应用前景。

关键词: 甲基六氢邻苯二甲酸酐, 乙二醇单丁醚, 抗磨剂, 抗磨性能, 低温性能

Abstract: Because of the ring tension of the cyclic structure, its low-temperature performance is better than that of long-chain alkanes. A series of monoester products were synthesized by esterification of several cyclic anhydride and alcohol (ethers) as raw materials, and their anti-wear effects and low-temperature performance were analyzed respectively. The research results showed that among the studied cyclic dicarboxylic acid monoester products, the methyl hexahydrophthalic anhydride (MHHPA) reacted with 2-Butoxyethanol (2-B) to prepare methyl hexahydrophthalic ethylene glycol butyl ether monoester (2-BM), which had both good anti-wear performance and low-temperature properties. With an additive amount of only 200 μg/g in ultra-low sulfur diesel, it can significantly improve the lubrication performance of diesel, reducing the average wear scar diameter (WSD) by 242 μm, decreasing the average friction coefficient by 51% and increasing the average oil film coverage by 10%.The freezing point of 2-BM is -42 ℃, which has a good application prospectat low-temperature conditions.

Key words: MHHPA, 2-butoxyethanol, anti-wear agent, anti-wear performance, low temperature performance