石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (6): 18-23.

• 加工工艺 • 上一篇    下一篇

高黏度油浆脱固技术探索

刘建新,马致远   

  1. 中海石油中捷石化有限公司
  • 收稿日期:2023-09-18 修回日期:2024-02-07 出版日期:2024-06-12 发布日期:2024-05-28
  • 通讯作者: 刘建新 E-mail:liujx8@cnooc.com.cn

EXPLORATION OF HIGH VISCOSITY OIL SLURRY DESOLIDIFICATION TECHNOLOGY


  • Received:2023-09-18 Revised:2024-02-07 Online:2024-06-12 Published:2024-05-28

摘要: 催化裂化外甩油浆(简称油浆)中的催化剂固体颗粒是影响其理化性质和高值化利用的瓶颈,因而油浆脱固技术成为油浆高值化深加工的关键突破口。鉴于目前主流的油浆脱固方法——药剂沉降法对高黏度油浆的脱固效果并不理想,以国内某炼油厂的油浆Z为研究对象,通过调节温度、引入稀释组分、加入黏度改性剂等方式改变油浆黏度,从而有效实现了高黏度油浆脱固。结果表明,将温度升高到130 ℃或加入质量分数0.1%的黏度改性剂,可将油浆脱固率提高到80%以上;通过加入柴油或芳烃溶剂油等稀释组分,可将油浆脱固率提高到95%以上。

关键词: 催化裂化, 油浆, 脱固率, 黏度, 黏度改性剂

Abstract: The solid particle of catalyst in FCC slurry is the bottleneck that affects its physical and chemical properties and high-value utilization. Therefore, slurry desolidification technology becomes the key breakthrough for further processing. Reagent sedimentation method is the main method of oil slurry desolidification, but the application effect is not ideal for high viscosity oil slurry. For further research, the slurry from a refinery was chosen as sample and named slurry Z. In order to reduce the ash content of the oil slurry, the viscosity of the oil slurry was changed by increasing the temperature, introducing dilution component and adding viscosity modifier. The results showed that the desolidification rate of the oil slurry could be increased to more than 80% by increasing the temperature to 130 ℃ or adding 0.1% viscosity modifier, and the desolidification rate of the oil slurry could be increased to more than 95% by adding dilution components such as diesel fraction or aromatic solvent oil.

Key words: catalytic cracking, oil slurry, desolidification rate, viscosity, viscosity modifier