CO2的N-甲酰化反应研究进展

摘要/Abstract

摘要： 二氧化碳（CO₂）的N-甲酰化反应是CO₂在还原剂的作用下，与有机胺类化合物反应生成N-甲酰胺类化合物的反应。CO₂的N-甲酰化反应既能够实现CO₂的资源化利用，有助于减少温室气体排放，同时能够将廉价的CO₂转化为高附加值的有机化学品，如N, N-二甲基甲酰胺和N-甲酰吗啉等，拓展CO₂下游转化利用的反应网络。对近年来CO₂的N-甲酰化反应的催化剂体系、催化机理和反应工艺等方面进行综述，阐述该反应研究过程中所面临的问题，并展望其未来发展方向。

关键词: CO₂, N-甲酰化, 催化剂, 反应工艺

Abstract: N-formylation of carbon dioxide (CO₂) is the reaction of CO₂with organic amine in the presence of a reducing agent to form N-formamide compound. The N-formylation reaction of CO₂ can be used as a resources to reduce greenhouse gas emissions, andcan convert cheap CO₂ into highvalue-added organic chemicals such as N,N-dimethylformamide and N-formylmorpholine,etc., expandsthe CO₂ downstream conversion and utilization of the reaction network. Inthis paper,the catalyst system, catalytic mechanism, and reaction process of N-formylation of CO₂ in recent yearswere reviewed, and the problems in the research and future developmentof the reactionwere also discussed.

Key words: CO₂, N-formylation, catalyst, reaction technology

郭旭何鑫徐润夏国富. CO₂的N-甲酰化反应研究进展[J]. 石油炼制与化工, 2024, 55(7): 152-162.

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CO₂的N-甲酰化反应研究进展

PROGRESS IN N-FORMYLATION OF CARBON DIOXIDE

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