钒基储氢合金的特点和应用前景

摘要/Abstract

摘要： 钒基储氢合金具有储氢密度高、储放氢反应条件温和、储氢动力学性能优越、抗粉化性能好等优点，是一种优良的储氢材料。但是钒基储氢合金存在放氢平台压低、可逆储氢量低、储放氢滞后现象明显、循环稳定性差、原料价格高、金属成本高等缺点，制约着钒基储氢合金进一步推广应用。迄今为止，研究者们从元素组成和晶相结构等多种途径对其进行改性，以优化钒基储氢材料性能。基于此，以降低氢化物的放氢平台压和提高材料可逆储氢量为出发点，简述了掺杂Ti，Cr，Mn，Zr等化学元素和对于储氢合金进行特定条件优化改善的研究进展，着重阐述了元素置换、材料热处理和合金活化预处理对钒基储氢合金储氢性能的影响，展望了钒基储氢合金未来发展前景。

关键词: 储氢, 钒基合金, 掺杂金属元素, 热处理, 表面处理

Abstract: Vanadium-based alloy is a good hydrogen storage material because of its high hydrogen storage capacity, mild hydrogenstorage and desorptionreaction conditions, excellent reaction kinetics properties of hydrogen storageand good anti-pulverization properties. However,vanadium-based hydrogen storagealloys have some disadvantages, such aslow hydrogen storage platform, low reversible hydrogen storage capacity, obvious hysteresis, poor cycle stability, high cost of raw materials and high metal cost, it restricts the further application of vanadium-based hydrogen storage alloys. So far, researchers have modified the vanadium-based hydrogen storage materials by many ways, such as elemental composition and crystalline phase structure, to optimize the performance of vanadium-based hydrogen storage materials. Based on this, the research progress of doping Ti, Cr, Mn, Zr and other chemical elementand the optimization of particular conditions for hydrogen storage alloys were briefly reviewed in order to reduce the platform pressure ofhydrogenation and increase the reversible hydrogen storage capacity of materials. The effects of element replacement, material heat treatment, and alloy activation pretreatmenton hydrogen storage properties of vanadium-based hydrogen storage alloys were emphasized. The future development prospect of vanadium-based hydrogen storage alloyswas prospected.

Key words: hydrogen storage, vanadium-based alloy, doping metal element, heat treatment, surface pretreatment

徐睿程涛杨雪荣峻峰. 钒基储氢合金的特点和应用前景[J]. 石油炼制与化工, 2024, 55(7): 163-169.

参考文献

参考文献
[1] Ye G, Xu X L, Chen Y, et al. Towards Green Economics and Society: Exploring the Efficiency of New Energy Generation[J]. Math Probl Eng, 2021, 2021:9950687.
[2] Li L, Luo L, Chen L, et al. Nanoscale microstructures and hydrogenation properties of an as-cast vanadium-based medium-entropy alloy[J]. Int J Hydrogen Energy, 2023, 48(75):29230-29239.
[3] Gmira S, Kobbane A, Ben-Othman J, et al. A New Energy Efficiency/Spectrum Efficiency Model for Cooperative Cognitive Radio Network[J]. Mobile Networks and Applications, 2018, 23(5):1436-1448.
[4] 李星国等编著. 氢与氢能[M].北京: 机械工业出版社, 2012.
[5] Züttel A. Materials for hydrogen storage[J]. Mater Today (Kidlington), 2003, 6(9):24-33.
[6] Yukawa H, Teshima A, Yamashita D, et al. Alloying effects on the hydriding properties of vanadium at low hydrogen pressures[J]. J Alloys Compd, 2002, 337(1):264-268.
[7] 裴沛, 张沛龙, 张蓓, et al. V系储氢合金及其合金化[J]. 材料导报, 2006, (10):123-127.
[8] Kumar S, Jain A, Ichikawa T, et al. Development of vanadium based hydrogen storage material: A review[J]. Renewable and Sustainable Energy Reviews, 2017, 72:791-800.
[9] Kumar S, Tiwari G P, Krishnamurthy N. Tailoring the hydrogen desorption thermodynamics of V2H by alloying additives[J]. J Alloys Compd, 2015, 645:S252-S256.
[10] Singh A, Maiya M P, Srinivasa Murthy S. Experiments on solid state hydrogen storage device with a finned tube heat exchanger[J]. Int J Hydrogen Energy, 2017, 42(22):15226-15235.
[11] Busqué R, Torres R, Grau J, et al. Effect of metal hydride properties in hydrogen absorption through 2D-axisymmetric modeling and experimental testing in storage canisters[J]. Int J Hydrogen Energy, 2017, 42(30):19114-19125.
[12] Afzal M, Mane R, Sharma P. Heat transfer techniques in metal hydride hydrogen storage: A review[J]. Int J Hydrogen Energy, 2017, 42(52):30661-30682.
[13] Song X P, Pei P, Zhang P L, et al. The influence of alloy elements on the hydrogen storage properties in vanadium-based solid solution alloys[J]. J Alloys Compd, 2008, 455(1):392-397.
[14] Yukawa H, Takagi M, Teshima A, et al. Alloying effects on the stability of vanadium hydrides[J]. J Alloys Compd, 2002, 330-332:105-109.
[15] Suwarno S, Solberg J K, M?hlen J P, et al. Non-isothermal kinetics and in situ SR XRD studies of hydrogen desorption from dihydrides of binary Ti–V alloys[J]. Int J Hydrogen Energy, 2013, 38(34):14704-14714.
[16] Hagi T, Sato Y, Yasuda M, et al. Structure and Phase Diagram of Ti–V–H System at Room Temperature[J]. Transactions of the Japan Institute of Metals, 1987, 28(3):198-204.
[17] Tamura T, Kazumi T, Kamegawa A, et al. Effects of Protide Structures on Hysteresis in Ti-Cr-V Protium Absorption Alloys[J]. Mater Trans, 2002, 43(11):2753-2756.
[18] Yan Y, Chen Y, Zhou X, et al. Some factors influencing the hydrogen storage properties of 30V–Ti–Cr–Fe alloys[J]. J Alloys Compd, 2008, 453(1):428-432.
[19] Yan Y, Chen Y, Liang H, et al. Hydrogen storage properties of V30–Ti–Cr–Fe alloys[J]. J Alloys Compd, 2007, 427(1):110-114.
[20] Nomura K, Akiba E. H2 Absorbing-desorbing characterization of the TiVFe alloy system[J]. J Alloys Compd, 1995, 231(1):513-517.
[21] 杭州明. Ti-V-Fe系储氢合金的微观结构及储氢性能研究[D]. 杭州: 浙江大学, 2010.
[22] Cho S, Enoki H, Akiba E. Effect of Fe addition on hydrogen storage characteristics of Ti0.16Zr0.05Cr0.22V0.57 alloy[J]. J Alloys Compd, 2000, 307(1):304-310.
[23] Nakamura Y, Nakamura J, Sakaki K, et al. Hydrogenation properties of Ti–V–Mn alloys with a BCC structure containing high and low oxygen concentrations[J]. J Alloys Compd, 2011, 509(5):1841-1847.
[24] Mouri T, Iba H. Hydrogen-absorbing alloys with a large capacity for a new energy carrier[J]. Materials Science and Engineering: A, 2002, 329-331:346-350.
[25] Basak S, Shashikala K, Kulshreshtha S K. Hydrogen absorption characteristics of Zr substituted Ti0.85VFe0.15 alloy[J]. Int J Hydrogen Energy, 2008, 33(1):350-355.
[26] Cho S, Han C, Park C, et al. Hydrogen storage characteristics of Ti–Zr–Cr–V alloys[J]. J Alloys Compd, 1999, 289(1):244-250.
[27] Yan Y, Chen Y, Liang H, et al. The effect of Si on V30Ti35Cr25Fe10 BCC hydrogen storage alloy[J]. J Alloys Compd, 2007, 441(1):297-300.
[28] Yan Y, Chen Y, Liang H, et al. Effect of Al on hydrogen storage properties of V30Ti35Cr25Fe10 alloy[J]. J Alloys Compd, 2006, 426(1):253-255.
[29] Jeng R, Lee S, Hsu C, et al. Effects of the addition of Pd on the hydrogen absorption–desorption characteristics of Ti33V33Cr34 alloys[J]. J Alloys Compd, 2008, 464(1):467-471.
[30] Huang L J, Lin H J, Wang H, et al. Amorphous alloys for hydrogen storage[J]. J Alloys Compd, 2023, 941:168945.
[31] Sakaki K, Kim H, Asano K, et al. Hydrogen storage properties of Nb-based solid solution alloys with a BCC structure[J]. J Alloys Compd, 2020, 820:153399.
[32] Aranda V, Leiva D R, Huot J, et al. Hydrogen storage properties of the TiVFeZr multicomponent alloy with C14-type laves phase structure[J]. Intermetallics (Barking), 2023, 162:108020.
[33] Wang M, Wang Y, Kong H, et al. Development of Fe-containing BCC Hydrogen Storage Alloys with High Vanadium Concentration[J]. J Alloys Compd, 2023:170294.
[34] Okada M, Kuriiwa T, Kamegawa A, et al. Role of intermetallics in hydrogen storage materials[J]. Materials Science and Engineering: A, 2002, 329-331:305-312.
[35] Tamura T, Kazumi T, Kamegawa A, et al. Protium absorption properties and protide formations of Ti–Cr–V alloys[J]. J Alloys Compd, 2003, 356-357:505-509.
[36] Rong M, Wang F, Wang J, et al. Effect of heat treatment on hydrogen storage properties and thermal stability of V68Ti20Cr12 alloy[J]. Progress in Natural Science: Materials International, 2017, 27(5):543-549.
[37] SUWARNO S, SOLBERG J K, MAEHLEN J P, et al. Microstructure and hydrogen storage properties of as-cast and rapidly solidified Ti-rich Ti–V alloys[J]. Trans Nonferrous Met Soc China, 2012, 22(8):1831-1838.
[38] Nakamura Y, Akiba E. New hydride phase with a deformed FCC structure in the Ti–V–Mn solid solution–hydrogen system[J]. J Alloys Compd, 2000, 311(2):317-321.
[39] Yu X, Wu Z, Li F, et al. Body-centered-cubic phase hydrogen storage alloy with improved capacity and fast activation[J]. Appl Phys Lett, 2004, 84(16):3199-3201.
[40] Song J, Wang J, Hu X, et al. Activation and Disproportionation of Zr2Fe Alloy as Hydrogen Storage Material[M]. 2019:1542
[41] Balcerzak M. Structure and hydrogen storage properties of mechanically alloyed Ti-V alloys[J]. Int J Hydrogen Energy, 2017, 42(37):23698-23707.
[42] Singh B K, Shim G, Cho S. Effects of mechanical milling on hydrogen storage properties of Ti0.32Cr0.43V0.25 alloy[J]. Int J Hydrogen Energy, 2007, 32(18):4961-4965.
[43] Reilly J J, Wiswall R H. Higher hydrides of vanadium and niobium[J]. Inorg Chem, 1970, 9(7):1678-1682.
[44] Kagawa A, Ono E, Kusakabe T, et al. Absorption of hydrogen by vanadium-rich VTi-based alloys[J]. Journal of the Less Common Metals, 1991, 172-174:64-70.
[45] Ono S, Nomura K, Ikeda Y. The reaction of hydrogen with alloys of vanadium and titanium[J]. Journal of the Less Common Metals, 1980, 72(2):159-165.
[46] Lynch J F, Reilly J J, Millot F. The absorption of hydrogen by binary vanadium-chromium alloys[J]. J Phys Chem Solids, 1978, 39(8):883-890.
[47] Seo C, Kim J, Lee P S, et al. Hydrogen storage properties of vanadium-based b.c.c. solid solution metal hydrides[J]. J Alloys Compd, 2003, 348(1):252-257.
[48] Tsukahara M. Hydrogenation Properties of Vanadium-Based Alloys with Large Hydrogen Storage Capacity[J]. Mater Trans, 2011, 52(1):68-72.
[49] Aoki M, Noritake T, Ito A, et al. Improvement of cyclic durability of Ti–Cr–V alloy by Fe substitution[J]. Int J Hydrogen Energy, 2011, 36(19):12329-12332.
[50] Towata S, Noritake T, Itoh A, et al. Effect of partial niobium and iron substitution on short-term cycle durability of hydrogen storage Ti–Cr–V alloys[J]. Int J Hydrogen Energy, 2013, 38(7):3024-3029.
[51] Abdul J M, Chown L H. Influence of Fe on hydrogen storage properties of V-rich ternary alloys[J]. Int J Hydrogen Energy, 2016, 41(4):2781-2787.
[52] Taxak M, Kumar S, Kalekar B B, et al. Effect of nickel addition on the solubility of hydrogen in tantalum[J]. Int J Hydrogen Energy, 2013, 38(18):7561-7568.
[53] Khrussanova M, Peshev P, Darriet B, et al. Hydrogen absorption by alloys of vanadium and some 3d-transition metals[J]. Mater Res Bull, 1992, 27(5):611-616.
[54] Massicot B, Latroche M, Joubert J M. Hydrogenation properties of Fe–Ti–V bcc alloys[J]. J Alloys Compd, 2011, 509(2):372-379.
[55] Kuriiwa T, Tamura T, Amemiya T, et al. New V-based alloys with high protium absorption and desorption capacity[J]. J Alloys Compd, 1999, 293-295:433-436.
[56] Challet S, Latroche M, Heurtaux F. Hydrogenation properties and crystal structure of the single BCC (Ti0.355V0.645)100?xMx alloys with M=Mn, Fe, Co, Ni (x=7, 14 and 21)[J]. J Alloys Compd, 2007, 439(1):294-301.
[57] Fuda T, Matsumoto K, Tominaga Y, et al. Effects of Additions of BCC Former Elements on Protium Absorbing Properties of Cr–Ti–V Alloys[J]. Materials Transactions, JIM, 2000, 41(5):577-580.
[58] Hang Z, Xiao X, Li S, et al. Influence of heat treatment on the microstructure and hydrogen storage properties of Ti10V77Cr6Fe6Zr alloy[J]. J Alloys Compd, 2012, 529:128-133.
[59] Young K, Ouchi T, Nei J, et al. Annealing effects on Laves phase-related body-centered-cubic solid solution metal hydride alloys[J]. J Alloys Compd, 2016, 654:216-225.
[60] Mu?oz C A P, Dewage H H, Yufit V, et al. A Unit Cell Model of a Regenerative Hydrogen-Vanadium Fuel Cell[J]. J Electrochem Soc, 2017, 164(14):F1717.
[61] Yufit V, Hale B, Matian M, et al. Development of a Regenerative Hydrogen-Vanadium Fuel Cell for Energy Storage Applications[J]. J Electrochem Soc, 2013, 160(6):A856.
[62] Goshome K, Endo N, Tetsuhiko M. Evaluation of a BCC alloy as metal hydride compressor via 100 MPa-class high-pressure hydrogen apparatus[J]. Int J Hydrogen Energy, 2019, 44(21):10800-10807.
[63] Pickering L, Reed D, Bevan A I, et al. Ti–V–Mn based metal hydrides for hydrogen compression applications[J]. J Alloys Compd, 2015, 645:S400-S403.
[64] Cao Z, Zhou P, Xiao X, et al. Investigation on Ti–Zr–Cr–Fe–V based alloys for metal hydride hydrogen compressor at moderate working temperatures[J]. Int J Hydrogen Energy, 2021, 46(41):21580-21589.
[65] Li C, Douglas Way J, Fuerst T F, et al. Low temperature hydrogen superpermeation in vanadium composite metal foil pumps[J]. Nucl Mater Energy, 2023, 37:101529.
[66] Tang S, Li L, Yan H, et al. Hydrogen trapping in vanadium carbide alloyed with transition metals[J]. Nucl Mater Energy, 2023, 36:101504.
[67] Fasolin S, Barison S, Boldrini S, et al. Hydrogen separation by thin vanadium-based multi-layered membranes[J]. Int J Hydrogen Energy, 2018, 43(6):3235-3243.