新型阴-非离子表面活性剂合成及其与高效表面活性剂18-AC之间的相互作用研究

石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (8): 92-98.

新型阴-非离子表面活性剂合成及其与高效表面活性剂18-AC之间的相互作用研究

张超,秦冰,江建林,乔富林

中石化石油化工科学研究院有限公司

收稿日期:2023-12-14 修回日期:2024-04-29 出版日期:2024-08-12 发布日期:2024-07-29
通讯作者: 乔富林 E-mail:qiaofulin.ripp@sinopec.com
基金资助:
国家重点研发计划“生物制剂复合驱油体系开发及应用示范”;国家自然科学基金青年基金“基于环糊精的寡聚阴离子表面活性剂的合成、其聚集及吸附行为及其对土壤中稠环芳烃污染物的增溶效果研究”

SYNTHESIS OF NOVEL ANIONIC-NONIONIC SURFACTANTS AND THEIR INTERACTION WITH HIGHLY INTERFACIAL ACTIVE SURFACTANT18-AC

Received:2023-12-14 Revised:2024-04-29 Online:2024-08-12 Published:2024-07-29

摘要/Abstract

摘要： 合成了不同碳数烷基链的新型阴-非离子表面活性剂，并通过表面张力技术研究了壬基酚聚氧乙烯醚硫酸钠（9-EOS）、十二烷基酚聚氧乙烯醚硫酸钠（12-EOS）与高效表面活性剂18-AC之间的相互作用。结果表明，9-EOS与高效表面活性剂18-AC之间存在拮抗作用，而长碳链的12-EOS与高效表面活性剂18-AC之间存在协同作用。此外，系统研究了复配体系对润湿性能、油水界面性能的影响，复配体系可以降低溶液在原油表面的接触角，具有较好的铺展效果。当12-EOS摩尔分数为0～0.6时，12-EOS与18-AC在润湿性能方面具有协同作用，接触角比单组分体系有所减小，且油水界面性能有所提升。

关键词: 表面活性剂, 分子间相互作用, 协同性

Abstract: anionic-nonionic surfactants with alkyl chains of different number of carbon atoms were synthesized, and the interaction between sodium nonylphenol polyoxyethylene ether sulfate (9-EOS), sodium dodecylphenol polyoxyethylene ether sulfate (12-EOS) and high performance surfactant (18-AC) was studied by surface tension technique. The results showed that there was an antagonistic effect between 9-EOS and 18-AC, while there was a synergistic effect between 12-EOS and 18-AC. In addition, the effects of the compound system on the wettability and oil-water interface properties of the mixtures were systematically studied. The compound system effectively reduced the contact angle on the crude oil surface. When the 12-EOS molar fraction is 0-0.6, the 12-EOS/18-AC system has a synergistic effect on the wettability, the contact angle is lower than that of individual surfactants, and the oil-water interface performance is improved.

Key words: surfactant, intermolecular interaction, synergistic

张超秦冰江建林乔富林. 新型阴-非离子表面活性剂合成及其与高效表面活性剂18-AC之间的相互作用研究[J]. 石油炼制与化工, 2024, 55(8): 92-98.

参考文献

[1]Geng, T; Zhang, C.; Jiang, Y.; et al.,.Synergistic effect of binary mixtures contained newly cationic surfactant: Interaction, aggregation behaviors and application properties.[J].Journal of Molecular Liquids, 2017, 232:36-44
[2]Wang, X; Yang, C..Synergistic interactions in the mixed micelles of anionic amino acid surfactant with cationic gemini surfactant.[J].The Journal of Chemical Thermodynamics, 2021, 162:106568-
[3]Jafari-Chashmi, P; Bagheri, A..The strong synergistic interaction between surface active ionic liquid and anionic surfactant in the mixed micelle using the spectrophotometric method.[J].Journal of Molecular Liquids, 2018, 269:816-823
[4]Singh, K; Marangoni, D. G..Synergistic interactions in the mixed micelles of cationic gemini with zwitterionic surfactants: The pH and spacer effect.[J].Journal of Colloid and Interface Science, 2007, 315:620-626
[5]Olayiwola, SO.; Dejam, M..Synergistic interaction of nanoparticles with low salinity water and surfactant during alternating injection into sandstone reservoirs to improve oil recovery and reduce formation damage.[J].Journal of Molecular Liquids, 2020, 317:114228-
[6]Luo, S; Wang, Y.; Wang, M.; et al..Synergistic Interaction and Aggregation Behavior in a Mixture of a Tripolar Zwitterionic Surfactant and an Anionic Surfactant.[J].Journal of Surfactants and Detergents, 2018, 21(6):899-908
[7]乔富林, 侯研博, 江建林等.低聚阳离子季铵盐表面活性剂与磺基两性表面活性剂之间的相互作用[J].科学技术与工程, 2019, 19(19):1-7
[8]Juhász, á; Tabajdi, R.; Dékány, I.; et al.,.Thermodynamic Characterization of Temperature- and Composition-Dependent Mixed Micelle Formation in Aqueous Medium. Thermodynamic Characterization of Temperature- and Composition-Dependent Mixed Micelle Formation in Aqueous Medium.[J].Journal of Surfactants and Detergents, 2017, 20(6):1291-1299
[9]Thomas, HG.; Lomakin, A.; Blankschtein, D.; et al.,.Growth of Mixed Nonionic Micelles.[J].Langmuir, 1997, 13(2):209-218
[10]Mahajan, RK.; Nandni, D.,.Micellization and Phase Behavior of Binary Mixtures of Anionic and Nonionic Surfactants in Aqueous Media.[J].Industrial & Engineering Chemistry Research, 2012, 51(8):3338-3349
[11]Schubert, BA.; Kaler, E. W.; Wagner, N. J.,.The Microstructure and Rheology of Mixed Cationic/Anionic Wormlike Micelles.[J].Langmuir, 2003, 19(10):4079-4089
[12]Tian, M; Zhu, L.; Yu, D.; et al.,.Aggregate Transitions in Mixtures of Anionic Sulfonate Gemini Surfactant with Cationic Ammonium Single-Chain Surfactant.[J].The Journal of Physical Chemistry B, 2013, 117(1):433-440
[13]Xu, H; Liu, B.; Kang, P.; et al.,.Properties of a Binary System Containing Anionic and Cationic Gemini Surfactants.[J].Journal of Surfactants and Detergents, 2015, 18(2):297-302
[14]Raghavan, SR.; Fritz, G.; Kaler, E. W.,.Wormlike Micelles Formed by Synergistic Self-Assembly in Mixtures of Anionic and Cationic Surfactants.[J].Langmuir, 2002, 18(10):3797-3803
[15]Bergstr?m, M.,.Synergistic Effects in Mixtures of an Anionic and a Cationic Surfactant.[J].Langmuir, 2001, 17(4):993-998
[16]Jadidi, N; Adib, B.; Malihi, F. B.,.Synergism and Performance Optimization in Liquid Detergents Containing Binary Mixtures of Anionic–Nonionic, and Anionic–Cationic Surfactants.[J].Journal of Surfactants and Detergents, 2013, 16(1):115-121
[17]Kumar, A; Mandal, A.,.Synthesis and physiochemical characterization of zwitterionic surfactant for application in enhanced oil recovery.[J].Journal of Molecular Liquids, 2017, 243:61-71
[18]Zhu, J; Qing, Y.; Wang, T.; et al.,.Preparation and characterization of zwitterionic surfactant-modified montmorillonites.[J].Journal of Colloid and Interface Science, 2011, 360(2):386-392
[19]Gerola, AP.; Costa, P. F. A.; Quina, F. H.; et al.,.Zwitterionic surfactants in ion binding and catalysis.[J].Current Opinion in Colloid & Interface Science, 2017, 32:39-47
[20]Chen, Z-Z.; Gang, H.-Z.; Liu, J.-F.; et al.,.A thermal-stable and salt-tolerant biobased zwitterionic surfactant with ultralow interfacial tension between crude oil and formation brine.[J].Journal of Petroleum Science and Engineering, 2019, 181:106181-
[21]Carmen, A, Albert, M., Félix, S.,.Perhydrotriquinacenic hosts. 1. Synthesis, complexation and transport properties of tripodands of C3 symmetry.[J].Tetrahedron, 1991, 47:5867-5876