石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (1): 117-122.

• 加工工艺 • 上一篇    下一篇

普通延迟焦化装置生产动力类负极焦研究

王慧,党建军,花飞   

  1. 中海油惠州石化有限公司
  • 收稿日期:2024-07-08 修回日期:2024-08-27 出版日期:2025-01-12 发布日期:2024-12-27
  • 通讯作者: 王慧 E-mail:wanghui68@cnooc.com.cn

STUDY ON THE PRODUCTION OF POWER CLASS CATHODE COKE IN CONVENTIONAL DELAYED COKING UNIT


  • Received:2024-07-08 Revised:2024-08-27 Online:2025-01-12 Published:2024-12-27

摘要: 随着锂离子电池负极材料行业的高速增长,其对石油焦原料的需求量越来越大,传统炼油厂如果能利用现有延迟焦化装置生产满足负极材料要求的焦原料,将是提质增效的有效途径。动力类电池要求负极材料能够实现高克容量、高倍率等性能,相应地要求负极材料焦原料有高比例的纤维结构和区域结构,这与焦化过程中碳质中间相的形成与生长密切相关。普通延迟焦化装置生产动力类负极焦需从原料和工艺条件两方面寻找改善途径,如掺炼催化裂化油浆,采用低反应温度、高焦化压力、大循环比、长生焦时间操作,并应对上下游衔接、加工效益评估、全厂物料平衡和维持石油焦品质稳定等方面的挑战。

关键词: 负极材料, 石油焦, 碳质中间相, 焦化

Abstract: With the high-speed growth of anode material industry, its demand for petroleum coke raw materials was getting bigger and bigger, and it was an effective way to improve quality and increase efficiency if traditional refineries can make use of the existing delayed coking unit to produce coke raw materials that meet the requirements of anode materials. Power batteries require anode materials to achieve high gram capacity, high multiplicity and other properties, and accordingly require anode material coke raw materials to have a high proportion of fiber structure and regional structure, which was closely related to the formation and growth of carbonaceous mesophase in the coking process. To produce power-class anode coke in ordinary delayed coking units, it was necessary to finding ways to improve both raw materials and process conditions, such as doping catalytic slurry, adopting low reaction temperature, high coking pressure, large cycle ratio, and long coke-growing time operation, and to meet the challenges of upstream and downstream convergence, comprehensive evaluation of processing efficiency, plant-wide material balance, and maintenance of stable petroleum coke quality.

Key words: anode material, petroleum coke, carbonaceous mesophase, coking