石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (1): 76-85.

• 基础研究 • 上一篇    下一篇

C8芳烃异构化径向床反应器数值模拟

党辉1,鲍迪1,唐晓津1,侯栓弟2,康承琳1   

  1. 1. 中石化石油化工科学研究院有限公司
    2. 中石化(大连)石油化工研究院有限公司
  • 收稿日期:2023-05-11 修回日期:2023-07-04 出版日期:2025-01-12 发布日期:2024-12-27
  • 通讯作者: 唐晓津 E-mail:tangxj.ripp@sinopec.com

NUMERICAL SIMULATION OF A RADIAL BED REACTOR FOR C8 AROMATICS ISOMERIZATION


  • Received:2023-05-11 Revised:2023-07-04 Online:2025-01-12 Published:2024-12-27

摘要: 为研究C8芳烃异构化径向床反应器内部流场分布和反应性能,建立了C8芳烃异构化径向床反应器模拟计算模型。通过引入多孔介质和反应动力学方程模型,对反应器内部流场和反应过程进行了模拟计算。结果表明,催化剂床层内,压力沿轴向由高到低呈下降趋势,速度呈现两端高、中间低的分布规律。沿径向方向,流体的流动压降较低。反应产物(对二甲苯)质量分数由扇形筒出口至中心管入口逐渐增大,且在不同轴向高度床层上变化规律相同。模拟计算得到的出口各组分质量分数与实际出口数据基本吻合,说明所建立的反应器模型能够较好地描述C8芳烃异构化径向床反应器的反应性能。

关键词: C8芳烃, 异构化, 径向床反应器, 计算流体力学, 反应动力学

Abstract: In order to research the distribution and reaction performance of the internal flow field of C8 aromatics heterogeneous radial bed, a simulation model for a radial bed reactor based on C8 aromatics isomerization process was developed. The model incorporates porous media and reaction kinetics equations to simulate the flow field and reaction processes within the reactor. The results indicate that within the catalyst bed, the pressure decreases along the axial direction, while the velocity follows a distribution pattern with higher values at the ends and lower values in the middle. In the radial direction, the pressure drop in the fluid flow is relatively low. The quality score of the reaction product (PX) gradually increases from the exit of the scallop to the central pipe, and the law changes on different axial height beds.The simulated mass fractions of individual components are in good agreement with the actual data, demonstrating that the developed reactor model can accurately describe the performance of the radial bed reactor for C8 aromatics isomerization.

Key words: C8 aromatics, isomerization, radial bed reactor, computational fluid dynamics, reaction kinetics