石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (2): 1-7.

• 催化剂 •    下一篇

催化裂化装置增产丁烯催化剂和助剂HBC系列的开发与应用

于善青,严加松,蔡凯,刘雨晴,郭硕   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2024-10-09 修回日期:2024-10-14 出版日期:2025-02-12 发布日期:2025-01-16
  • 通讯作者: 严加松 E-mail:yanjs.ripp@sinopec.com
  • 基金资助:
    国家重点研发计划

DEVELOPMENT AND APPLICATION OF HBC SERIES CATALYST AND ADDITIVE FOR BOOSTING BUTENES IN FCC UNIT

  • Received:2024-10-09 Revised:2024-10-14 Online:2025-02-12 Published:2025-01-16

摘要: 中石化石油化工科学研究院有限公司开发了HBC系列增产丁烯的催化裂化催化剂和助剂,通过新型催化材料和制备技术优化等措施,强化催化裂化过程正碳离子的异构化反应和抑制氢转移反应,促进烃类分子向丁烯的定向转化。在工业应用过程中,HBC-A催化剂表现出兼具增产丁烯和增强重油裂化能力的特点,在液化气收率变化不大的情况下,丁烯(对原料)收率增加0.5百分点以上,柴油和油浆产率降低;HBC-B助剂可灵活与主催化剂按照适当比例掺混使用,表现出优异的丁烯选择性和适当的柴油转化能力,当HBC-B助剂占系统催化剂藏量(w)的5.0%时,丁烯(对原料)收率增加0.5~1.0百分点以上,柴油产率降低,汽油收率变化不大或略有增加。

关键词: 催化裂化, 丁烯, 催化剂, 助剂, 汽油, 柴油

Abstract: HBC series catalyst and additive for boosting butenes in FCC unit have been developed by SINOPEC Research Institute of Petroleum Processing Co., Ltd., enhancing the isomerization of carbocation ions and inhibiting the hydrogen transfer reaction in the catalytic cracking process to promote the directional conversion of hydrocarbon molecules to butenes, with the new catalytic materials and optimized preparation techniques. In the commercial application, HBC-A catalyst shows the abilities of both increasing butenes and enhancing bottom cracking, the butene yield increased by more than 0.5 percentage point, while the yield of light cycle oil (LCO) and slurry decreased. HBC-B additive can be flexibly mixed with the main catalyst according to a proper proportion, showing excellent butene selectivity and certain LCO conversion ability. When HBC-B accounts for 5.0% of the catalyst inventory in the system, the butenes yield increased by 0.5~1.0 percentage point, the LCO yield decreased, and the gasoline yield changed little or increase slightly.

Key words: catalytic cracking, butene, catalyst, additive, gasoline, diesel