石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (7): 128-135.

• 控制与优化 • 上一篇    下一篇

对二甲苯提纯装置短周期运行模拟研究

国钰奇,王德华,朱宁   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2024-12-25 修回日期:2025-02-28 出版日期:2025-07-12 发布日期:2025-07-01
  • 通讯作者: 王德华 E-mail:wangdh.ripp@sinopec.com
  • 基金资助:
    中国石油化工股份有限公司合同项目

SIMULATION STUDY ON SHORT-CYCLE OPERATION OF p-XYLENE PURIFICATION UNIT


  • Received:2024-12-25 Revised:2025-02-28 Online:2025-07-12 Published:2025-07-01

摘要: 建立了模拟移动床吸附分离对二甲苯过程的模型,研究了循环周期、吸附塔各区域回流比对吸附分离过程吸附性能的影响。模拟结果显示:保持各区域回流比不变,随着循环周期逐渐缩短,装置生产质量空速大幅度提高,对二甲苯纯度、收率指标逐渐降低,循环周期在24 min以上时,对二甲苯产品仍可保持较高纯度,收率小幅度降低;继续缩短循环周期,需要调整区域回流比来保证产品纯度。在保证产品纯度的前提下,在循环周期为17.6min时得到最大质量空速,但此时收率较低,为82.2%,单位产品的解吸剂用量比循环周期为32min时提高约19.9%。

关键词: 模拟移动床, 过程模拟, 吸附分离, 对二甲苯

Abstract: A model was established to simulate the process of p-xylene adsorption and separation on a moving bed to study the effects of the cycle period and the reflux ratios of each area of the adsorption tower on the adsorption performance of the adsorption and separation process. The simulation results show that: keeping the reflux ratio of each region unchanged, with the gradual shortening of the cycle period, the production WHSV is greatly increased, the purity of paraxylene and the yield indexes are gradually reduced, and when the cycle period is more than 24 min, the paraxylene product can still maintain a higher purity, and the yield is slightly reduced; to continue to shorten the cycle period, the reflux ratio of each region needs to be adjusted to ensure the purity of the product. Under the premise of ensuring product purity, the maximum production WHSV was obtained at a cycle time of 17.6 min, but at this time, the yield was lower at 82.2%, and the desorbent dosage per unit of product was about 19.9% higher than that at a cycle time of 32 min.

Key words: simulated moving bed, process simulation, adsorptive separation, p-xylene