石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (7): 13-23.

• 加工工艺 • 上一篇    下一篇

基于突变相转变法的高沥青含量乳化沥青制备及性能研究

窦和潮1,王瑞育2,苏记华1,张伟1,武文鑫3,孙晓1,张德岩1,赵品晖2   

  1. 1. 中铁十四局集团第四工程有限公司
    2. 山东建筑大学交通工程学院
    3. 山东高速交通建设集团有限公司
  • 收稿日期:2024-11-19 修回日期:2025-01-14 出版日期:2025-07-12 发布日期:2025-07-01
  • 通讯作者: 张伟 E-mail:554035615@qq.com
  • 基金资助:
    山东省自然科学基金

FABRICATION AND CHARACTERIZATION RESEARCH ON HIGH-ASPHALT-CONTENT EMULSIFIED ASPHALT BASED ON CATASTROPHIC PHASE INVERSION

  • Received:2024-11-19 Revised:2025-01-14 Online:2025-07-12 Published:2025-07-01
  • Supported by:
    基于材料基因组的咪唑啉沥青乳化剂的设计、合成及构效关系研究

摘要: 提高乳化沥青中的沥青含量可以有效改善沥青混合料的路用性能,基于此采用突变相转化法制备沥青质量分数大于75%的高沥青含量乳化沥青(HIACEs)。通过分散性试验、电导率试验、粒径试验、贮存稳定性试验和蒸发残留物试验等研究HIACEs的制备工艺及其性能变化规律。结果表明,形成水包油型HIACEs所能“容纳”的最大沥青质量分数为96%。随着沥青含量、乳化剂掺入量、搅拌时间、搅拌速率的增加,HIACEs的平均粒径减小并趋于稳定,贮存稳定性逐渐变好。通过正交试验进一步确定制备工艺条件对HIACEs性能影响由大到小的顺序为:沥青含量>乳化剂掺入量>搅拌速率。较优的HIACEs制备工艺条件为:沥青质量分数89%,乳化剂质量分数4%,搅拌时间10 min,搅拌速率1000 r/min。研究结果可为HIACEs的生产和应用提供理论基础和技术支持。

关键词: 乳化沥青, 高沥青含量, 突变相转变, 制备过程

Abstract: Increasing the asphalt content in asphalt emulsion can effectively improve the road performance of asphalt mixtures. Based on this, the phase inversion method was adopted to prepare high-asphalt-content asphalt emulsions (HIACEs) with an asphalt mass fraction greater than 75%. The preparation process and the influence mechanisms of HIACEs' performance were studied through dispersibility tests, conductivity tests, particle size tests, storage stability tests, and residue evaporation tests. The results showed that the maximum asphalt mass fraction that could be "accommodated" in water-in-oil HIACEs was 96%. With the increase in asphalt content, emulsifier dosage, stirring time, and stirring rate, the average particle size of HIACEs decreased and stabilized, while the storage stability gradually improved. Orthogonal experiments further determined that the order of influence of preparation process conditions on HIACEs' performance decreased following: asphalt content > emulsifier content > stirring rate. The optimal preparation conditions for HIACEs were:an asphalt mass fraction of 89%, an emulsifier mass fraction of 4%,a stirring time of 10 min, and a stirring rate of 1000 r/min. The research results provide a theoretical foundation and technical support for the production and application of HIACEs.

Key words: emulsified asphalt, high asphalt content, catastrophic phase inversion, fabrication process