石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (9): 10-19.

• 基础研究 • 上一篇    下一篇

拟薄水铝石及γ-Al2O3制备工艺模型构建与分析

杨帆,杨彦鹏,孟繁磊,苗成林,王杰广   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2025-02-20 修回日期:2025-03-25 出版日期:2025-09-12 发布日期:2025-08-28
  • 通讯作者: 杨彦鹏 E-mail:yangyp.ripp@sinopec.com
  • 基金资助:
    “十四五”国家重点研发计划项目

CONSTRUCTION AND ANALYSIS OF PROCESS MODELS FOR PREPARATION OF PSEUDO-BOEHMITE AND γ-Al2O3


  • Received:2025-02-20 Revised:2025-03-25 Online:2025-09-12 Published:2025-08-28
  • Contact: Yanpeng YanYang E-mail:yangyp.ripp@sinopec.com

摘要: 基于烷氧基铝水解制备拟薄水铝石及γ-Al2O3的工艺数据集,构建了制备工艺条件与拟薄水铝石及γ-Al2O3的孔体积、比表面积间的分段线性回归模型,并确定了最优模型结构。各模型的调整决定系数(R2)均表现良好,且均通过了分段变量的Davies显著性检验。这表明,在保持模型结构简洁的同时,分段线性回归模型能够提供较高的拟合精度,且具有合理的复杂度和较强的稳定性,能够有效揭示制备工艺参数与产物物理性质之间复杂的内在联系。验证结果显示,利用各模型在已知制备条件下对拟薄水铝石及γ-Al2O3的孔体积、比表面积进行预测,其最大相对误差不超过4.80%。构建的模型具有较高的精度,可用于指导拟薄水铝石及γ-Al2O3制备条件设计和物化性质预测,对实现拟薄水铝石及γ-Al2O3物化性质的精准调控具有重要意义。

关键词: 拟薄水铝石, γ-Al2O3, 制备工艺, 分段线性回归模型

Abstract: Based on the dataset of the hydrolysis process for preparing pseudo-boehmite and γ-Al2O3 from aluminum alkoxide, segmented linear regression models were constructed to link the preparation conditions with the pore volume and specific surface area of pseudo-boehmite and γ-Al2O3, and the optimal model structures were determined. The adjusted coefficient of determination(R2) of all models were satisfactory, and all models passed the Davies significancetest for segmented variables. This indicates that, while maintaining model simplicity, segmented linear regression models can provide high fitting accuracy, reasonable complexity, and strong stability, effectively revealing the complex intrinsic relationships between preparation parameters and the physicochemical properties of the products. Validation results showed that the maximum relative error in predicting the pore volume and specific surface area of pseudo-boehmite and γ-Al2O3 under known preparation conditions was no more than 4.80%. The models developed in this study have high precision and can be used to guide the design of preparation conditions and predict the physicochemical properties of pseudo-boehmite and γ-Al2O3, providing significant guidance for the precise control of their physicochemical properties.

Key words: pseudo-boehmite, γ-Al2O3, preparation process, segmented linear regression model