石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (10): 107-114.

• 基础研究 • 上一篇    下一篇

精馏分离C10~C13正构烷烃单体的模拟与实验研究

柳永兵1,陈鹏程1,刘朋1,张艳1,孙晨晨1,邹斌1,李彦飞1,张学光2   

  1. 1. 陕西未来能源化工有限公司煤制油分公司
    2. 天津海成能源工程技术有限公司
  • 收稿日期:2026-03-30 修回日期:2026-07-08 出版日期:2026-10-12 发布日期:2026-09-20
  • 通讯作者: 张学光 E-mail:1942069374@qq.com

SIMULATION AND EXPERIMENTAL STUDY ON SEPARATION OF C10—C13 n-ALKANE MONOMERS BY DISTILLATION

  • Received:2026-03-30 Revised:2026-07-08 Online:2026-10-12 Published:2026-09-20

摘要: 为了解决传统液体石蜡生产能耗高、产能低、操作复杂的缺点,以轻质液体石蜡为原料,通过精馏分离得到C10~C13高纯度正构烷烃单体产品,模拟该分离过程并优化工艺参数以得到最佳操作条件,实现大规模生产。使用Aspen Plus软件对精馏分离过程进行初步模拟,开展小试分离试验对模拟结果进行验证。分别考察精馏分离过程中理论塔板数、原料进料塔板编号、塔顶馏出量和回流比对精馏分离的影响,得到最佳操作参数及分离结果。通过试验验证,产品质量和收率的模拟值与试验值基本吻合,精馏分离方案可行且模拟结果较为准确,通过后续模拟优化得到最优操作参数及模拟结果,可为后续工业化生产提供依据。

关键词: 烷烃, 精馏, 模拟, 优化设计

Abstract: To address the drawbacks of traditional liquid paraffin production—high energy consumption, low capacity, and complex operations, this study uses light liquid paraffin as feedstock to produce high-purity C10–C13 n-alkane monomers via distillation. The separation process was simulated, and process parameters were optimized to determine optimal operating conditions for large-scale production. The distillation separation process was preliminarily simulated using Aspen Plus software, and pilot-scale separation experiments were conducted to validate the simulation results. The effects of the theoretical number of trays,feed point,overhead flow rate,and reflux ratio on the distillation separation process were investigated to determine the optimal operating parameters and separation results.Experimental validation confirmed that the simulated values for product quality and yield were in close agreement with the experimental data. The distillation separation scheme is feasible, and the simulation results are relatively accurate. Through subsequent simulation optimization, optimal operating parameters and simulation results were obtained, providing a basis for subsequent industrial-scale production.

Key words: alkane, distillation, simulation, optimal design