石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (10): 20-25.

• 催化剂 • 上一篇    下一篇

SKI-320催化剂在C8芳烃异构化升级改造装置上的工业应用

岳欣1,刘中勋1,常超2,康承琳1   

  1. 1. 中石化石油化工科学研究院有限公司
    2. 福建联合石油化工有限公司
  • 收稿日期:2026-04-02 修回日期:2026-06-26 出版日期:2026-10-12 发布日期:2026-09-20
  • 通讯作者: 岳欣 E-mail:yuexin.ripp@sinopec.com

COMMERCIAL APPLICATION OF SKI-320 CATALYST IN THE UPGRADED REACTOR FOR C8 AROMATICS ISOMERIZATION

  • Received:2026-04-02 Revised:2026-06-26 Online:2026-10-12 Published:2026-09-20

摘要: SKI-320乙苯脱乙基型C8芳烃异构化催化剂在炼化企业A的1.0 Mt/a对二甲苯的芳烃联合单元C8芳烃异构化升级改造装置上成功进行了应用。为配合扩能需求,对异构化反应器内部构件进行改造,加设开孔隔离挡板,构建出的催化剂床层参数与炼化企业B原生设计为脱乙基工艺的床层参数十分接近,保障最大程度发挥SKI-320催化剂的性能。催化剂装填过程稳定可控,开工操作简便,投用后运行情况良好。标定结果显示:单程二甲苯异构化率达到 23.82%,乙苯转化率达到 68.32%,二甲苯收率为98.87%,首次通过对转化型反应器进行径向改造实现了与原生设计装置相当的工业运行效果。

关键词: 脱乙基型, C8芳烃异构化, 催化剂, 内构件, 反应器

Abstract: SKI-320 dealkylation type catalyst for C8 aromatics isomerization has been commercialized in a 1.0 Mt/a aromatic combination plant of Company A. To realize the capacity expansion requirements, the internal components of the isomerization reactor were modified by installing perforated isolation baffles, the resulting catalyst bed parameters closely match those of refining Company B’s original design for dealkylation processes, ensuring optimal performance of the SKI-320 catalyst. The loading of the catalyst is controllable and stable, and the catalyst is started up smoothly and easily. After being put into use,the catalyst shows good performance during operation. Performance benchmarking showed: single-pass xylene isomerization rate reached 23.82%, ethylbenzene conversion rate achieved 68.32%, and xylene yield was 98.87%. This marks the first successful industrial-scale demonstration of a upgraded reactor achieving performance comparable to that of an originally designed unit.

Key words: dealkylation type, C8 aromatics isomerization, catalyst, internals, reactor