石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (2): 207-212.

• 研究报告 • 上一篇    下一篇

催化裂化油浆的性质组成与结构分析

吴富卜,崔文龙,李永旭,钱俊峰,梁倩   

  1.  江苏省绿色催化材料与技术重点实验室,高端化学品先进制造省高校重点实验室,江苏省先进催化与绿色制造协同创新中心, 常州大学石油化工学院
  • 收稿日期:2025-10-20 修回日期:2025-11-11 出版日期:2026-02-12 发布日期:2026-01-27
  • 通讯作者: 吴富卜 E-mail:1741962257@qq.com
  • 基金资助:
    江苏省研究生科研与实践创新计划项目;江苏省自然科学基金资助课题;重质油国家重点实验室开放基金资助项目;江苏省精细石油化工重点实验室开放课题基金资助项目

ANALYSIS OF PROPERTIES COMPOSITION AND STRUCTURE OF FCC SLURRY


  • Received:2025-10-20 Revised:2025-11-11 Online:2026-02-12 Published:2026-01-27

摘要: 催化裂化油浆(简称油浆)作为催化裂化过程的副产物,可用于制备高端功能碳材料,深入分析其性质、组成与结构特点对进一步加工处理和高附加值利用具有重要意义。以油浆为研究对象,在考察基本性质和组成的基础上,采用核磁共振波谱仪、傅里叶变换红外光谱仪、扫描电子显微镜、X射线衍射仪、激光粒度仪等仪器表征其结构,结合改进的Brown-Ladner法计算平均结构参数。研究结果表明,油浆具有高密度、高黏度、高固含量的特点,灰分为0.49%,芳香分质量分数达69.48%,氢碳原子比为1.07,平均分子结构为3.01个环的渺位缩合芳香环系,其中的固体颗粒为不规则形态,由分子筛催化剂粉末聚集形成,粒径主要分布于1~10μm。

关键词: 催化裂化油浆, 催化剂, 沥青质, 平均分子结构

Abstract: Fluid catalytic cracking(FCC) slurry as the by-product of the FCC process, can be used to prepare high-end functional carbon materials. It is of great significance to analyze its properties and structural characteristics for further processing and high-value-added utilization. Based on the investigation of basic properties and compositions, the structure of the slurry was characterized by NMR, FTIR, SEM, XRD, and a laser particle size analyzer. The average structural parameters were calculated by the improved Brown-Ladner method. The results show that slurry has the characteristics of high density, high viscosity, and high solid content. The ash content is 0.49%, the aromatic content is 69.48%, the H/C atom ratio is 1.07, and the average molecular structure is acondensed aromatic ring systemwith3.01 rings. The solid particles in theslurry are irregular in shape and formed from the aggregation of molecular sieve catalyst powder. The particle size is mainly distributed in 1—10μm.

Key words: FCC slurry, catalyst, asphaltene, average molecular structure