石油炼制与化工 ›› 2026, Vol. 58 ›› Issue (7): 12-18.

• 加工工艺 • 上一篇    下一篇

重烯烃催化裂化加工技术路线研究

王迪,魏晓丽,刘宪龙,龚剑洪   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2025-12-25 修回日期:2026-04-02 出版日期:2026-07-12 发布日期:2026-06-29
  • 通讯作者: 龚剑洪 E-mail:gongjh.ripp@sinopec.com
  • 基金资助:
    重烯烃催化裂化加工技术路线研究

RESEARCH ON THE TECHNICALAPPROACHES FOR CATALYTIC CRACKING PROCESSING OF HEAVY OLEFINS


  • Received:2025-12-25 Revised:2026-04-02 Online:2026-07-12 Published:2026-06-29

摘要: 为了高值化利用甲醇制烯烃装置副产的重烯烃,采用小型固定流化床装置,考察了重烯烃的催化裂化反应性能和产物性质,并分析了其对加工过程和与重油共加工时对产品性质的影响。结果表明:重烯烃中的杂原子含量较低,对加工过程和产品质量的影响可忽略;重烯烃在催化裂化反应过程中可高效转化为低碳烯烃和汽油;重烯烃与重油原料共同作为催化裂化反应原料时,在两种不同反应方式中,随着重烯烃在原料中的比例增加,汽油产率均提高,辛烷值提高,汽油中二烯烃含量均较低,对汽油性质影响不大。

关键词: 重烯烃, 催化裂化, 低碳烯烃, 高辛烷值汽油

Abstract: In order to maximize the value of heavy olefins, by-products from methanol-to-olefins unit, their catalytic cracking performance and product properties were investigated using ACE and FFB units. The impact of heavy olefins on processing and product quality when co-processed with heavy oil was also analyzed. The results indicated that the influence on the processing and product quality was negligible because of the low heteroatom content in heavy olefins. Heavy olefins can be efficiently converted into light olefins and gasoline by catalytic cracking reaction. When heavy olefins were co-processed with heavy oil, in both reaction modes, as the proportion of heavy olefins in the feed increased, gasoline yield rised and the octane number improved, the diene content in gasoline remained low, indicating minimal impact on gasoline properties.

Key words: heavy olefins, catalytic cracking, light olefins, high-octane gasolin