石油炼制与化工 ›› 2014, Vol. 45 ›› Issue (8): 22-27.

• 催化剂 • 上一篇    下一篇

劣质柴油加氢改质催化剂的制备及其应用 Ⅱ.共胶法加氢改质催化剂的应用

梁吉雷1,王利强1,2,柳云骐1,刘晨光1   

  1. 1. 中国石油大学(华东)重质油国家重点实验室 CNPC催化重点实验室

      2. 中国石油集团工程设计有限责任公司华北分公司
  • 收稿日期:2013-12-31 修回日期:2014-02-08 出版日期:2014-08-12 发布日期:2014-07-22
  • 通讯作者: 柳云骐 E-mail:liuyq@upc.edu.cn
  • 基金资助:

    国家重点基础研究发展计划(973)项目;国家自然科学基金项目;中央高校基本科研业务费专项基金项目;高等学校博士学科点专项科研基金博导类资助课题

PREPARATION AND APPLICATION OF HYDROUPGRADING CATALYST FOR INFERIOR DIESEL Part II.PERFORMANCE OF HYDROUPGRADING CATALYST PREPARED BY CO-GELLING

  • Received:2013-12-31 Revised:2014-02-08 Online:2014-08-12 Published:2014-07-22

摘要: 通过共胶法制备了一种非负载型加氢改质催化剂。采用X射线衍射、NH3-程序升温脱附、吡啶吸附红外光谱、扫描电子显微镜、N2吸附-脱附等手段对制备的催化剂进行表征。以中国石化青岛炼油化工有限责任公司(简称青岛炼化)和石大科技胜华炼油厂(简称胜华)两种劣质催化裂化(FCC)柴油为原料,考察催化剂的脱硫、脱氮、脱芳烃效果及其对高硫、高芳烃劣质柴油原料的适应性。结果表明:共胶法催化剂可在360 ℃下使青岛炼化FCC柴油硫质量分数由7 428 μg/g降到14 μg/g、胜华FCC柴油硫质量分数由5 114 μg/g降到12 μg/g,能够完全脱除两种劣质FCC柴油中的氮化物,且对FCC柴油的稠环芳烃脱除率达99%以上。

Abstract: An unsupported diesel hydroupgrading catalyst was prepared by co-geling and characterized by N2 adsorption-desorption isotherms, XRD, NH3-TPD, Py-IR and SEM. The catalyst was evaluated by two different FCC diesels for the hydrodesulfurization, hydrodenitrogeneration and hydrodearomatization and tested the feed adaptability for high S and aromatics inferior feedstocks. The results show that at a temperature of 360 ℃, for the Qingdao FCC diesel consisting of difficult to be removed DBTs as the main S-containing compounds, the sulfur content can be reduced to 15 μg/g from 7 428 μg/g; for the Shenghua FCC diesel consisting of easily removed BTs as the main S-containing compounds, the sulfur content can be reduced to 14 μg/g from 5 114 μg/g. The catalyst can remove the N-containing compounds completely in the two FCC diesels. Besides, polycyclic aromatic hydrocarbons in the two FCC diesels can be removed by up to 99%.