石油炼制与化工 ›› 2014, Vol. 45 ›› Issue (8): 35-39.

• 加工工艺 • 上一篇    下一篇

催化裂化油浆溶剂萃取生产环保橡胶油和裂化原料研究

王延臻1,李金云2,董艳丽3,段红玲1   

  1. 1. 中国石油大学(华东)重质油国家实验室
      2. 中国石油大学胜利学院
      3. 神华宁夏煤业集团煤化工分公司
  • 收稿日期:2014-02-21 修回日期:2014-03-15 出版日期:2014-08-12 发布日期:2014-07-22
  • 通讯作者: 李金云 E-mail:slythxxl@sohu.com

PREPRATION OF ENVIRONMENTAL RUBBER OIL AND CRACKING MATERIAL FROM FCC SLURRYY BY SOLVENT EXTRACTION

  • Received:2014-02-21 Revised:2014-03-15 Online:2014-08-12 Published:2014-07-22

摘要: 以糠醛为萃取溶剂、石油醚为助溶剂,采用错流和逆流两种萃取方式,研究了催化裂化油浆生产环保型橡胶填充油或催化裂化原料的方法,考察了萃取温度、剂油比和萃取级数的影响。结果表明:单级萃取的最优条件为萃取温度50 ℃、剂油比2.5:1,在此最优条件下,萃取级数越高,萃取效果越好,当萃取级数达到三级时,两种工艺所得精制油多环芳烃质量分数(PCA)3%以下,8种致癌性多环芳烃PAHs<10 μg/g,芳碳率10%以上,均满足欧盟环保型橡胶油要求;同时精制油密度降到0.9 g/cm3以下,饱和烃含量达到80%以上,也是优质催化裂化原料。多级逆流萃取精制油收率可达到30%以上,明显高于多级错流萃取。

Abstract: The environmental rubber oil or FCC feedstock were prepared from FCC slurry using furfural as a extract solvent and petroleum ether as a co-solvent. The influence factors of extract temperature, solvent/oil ratio and extraction stages were investigated by crosscurrent extraction and countercurrent extraction process. The results show that the optimum conditions for single-stage extraction were: extraction temperature of 50 ℃ and solvent/oil ratio of 2.5:1. At this condition the extraction effect becomes better with the extraction stage increasing. At three extraction stages, the polycyclic aromatic hydrocarbons (PCA) content of the refined oil obtained from the two processes were both less than 3% and their aromatic carbon rates were above 10%, meeting the EU requirements for environmental rubber oils. At the same time, the density of the refined oil was dropped below 0.9g/cm3 and the saturated hydrocarbon content reaches above 80%, which was considered to be a qualified FCC feedstock. The yield of the refined oil obtained from the multi-stage countercurrent extraction process reaches above 30%, remarkably higher than the yield obtained from the crosscurrent extraction process.