石油炼制与化工 ›› 2014, Vol. 45 ›› Issue (8): 92-96.

• 油品与添加剂 • 上一篇    下一篇

变压器油比热容的影响因素考察

王会娟1,2,于会民1,2,马书杰1,2,张绮1,2   

  1. 1. 中国石油兰州润滑油研究开发中心
      2. 中国石油天然气集团公司润滑油重点实验室
  • 收稿日期:2014-01-29 修回日期:2014-03-27 出版日期:2014-08-12 发布日期:2014-07-22
  • 通讯作者: 王会娟 E-mail:wanghuijuan_rhy@petrochina.com.cn
  • 基金资助:

    中国石油润滑油公司项目

FACTORS AFFECTING HEAT CAPACITY OF TRANSFORMER OIL

  • Received:2014-01-29 Revised:2014-03-27 Online:2014-08-12 Published:2014-07-22

摘要: 采用流动型比热容测量法考察了温度、黏度、精制深度、烃组成等对变压器油比热容的影响。结果表明:依据ASTM D2766—1995设计的流动型比热计测量法相比ASTM E1269-2005法,重复性更好,误差在±2%以内;在-20~100 ℃范围内,变压器油比热容随温度升高呈近似线性增大的趋势;在传统溶剂精制过程中,变压器油比热容受精制深度的影响不大;黏度相近时,芳碳含量对变压器油的比热容影响不大;黏度相近时,变压器油比热容随链烷碳含量的增大而增大,且链烷碳含量较大的变压器油比热容随温度升高而增大的程度略小,100 ℃时不同链烷碳含量变压器油的比热容非常接近;对于同一油源、同一工艺得到的不同馏程的基础油,黏度增加3倍时,比热容只增大2.6%,其比热容随黏度的增加呈略增大趋势。

Abstract: In this work, several liquid specific heat capacity measuring methods were introduced. The effect of temperature,viscosity,refining depth and hydrocarbon composition on the specific heat capacity of transformer oil were investigated using the measuring methods. It is found that the repeatability of flow calorimetric method(ASTM D2766—1995) with the deviation less than ±2%, is better than that of the differential scanning calorimetry (ASTM E1269-2005) method. The investigation finds that the specific heat capacity of transformer oil increases linearly with increasing temperature in the range of -20—100 ℃. The heat capacity of the oils by traditional solvent refining is hardly affected by refining depth and additives. The test results show that for the oils with the same viscosity but different aromatic contents, the heat capacities are basically the same and that the heat capacities are directly related to alkane content but increases slowly with temperature for the higher alkane content oils. As a result, the heat capacities of the oils with different alkane content are very close at 100℃. While for oils from the same oil sources, refining process and having similar carbon type composition but different boiling range, even the viscosity increases three times, the heat capacity only increases 2.6%,indicating the slightly increase of heat capacity with viscosity..