石油炼制与化工 ›› 2014, Vol. 45 ›› Issue (9): 95-101.

• 节能减排 • 上一篇    下一篇

炼油厂恶臭废气综合治理技术的研究 Ⅰ.酸性水罐区和轻质油品中间罐区废气治理技术

郭兵兵1,刘忠生1,王海波1,华秀凤2   

  1. 1. 中国石化抚顺石油化工研究院
      2. 中国石油抚顺石化公司石油三厂
  • 收稿日期:2014-02-08 修回日期:2014-04-22 出版日期:2014-09-12 发布日期:2014-08-19
  • 通讯作者: 郭兵兵 E-mail:guobb505@163.com
  • 基金资助:

    中国石油化工股份有限公司合同项目

COMPREHENSIVE TREATMENT TECHNOLOGY FOR ODOUR POLLUTION OF WASTE GAS IN REFINER Ⅰ.STUDY OF TREATMENT TECHNOLOGY FOR WASTE GAS FROM SOUR WATER TANK AND LIGHT PRODUCT TANK

  • Received:2014-02-08 Revised:2014-04-22 Online:2014-09-12 Published:2014-08-19

摘要: 监测和分析了某典型炼油厂酸性水储罐和油品中间罐排放气组成和排放规律,采用罐区减排和“低温馏分油临界吸收-脱硫”等多种措施综合治理罐区排放废气。结果表明:罐区排放的恶臭污染物主要为硫化氢、甲硫醇、乙硫醇、二甲二硫、非甲烷烃等;酸性水罐排放废气中硫化氢浓度为100~4.21×104 mg/m3,有机硫化物浓度为112~1.39×103 mg/m3,非甲烷总烃浓度为(1.52~4.78)×105 mg/m3;油品中间罐区排放废气中硫化氢浓度为175~3.36×103 mg/m3,有机硫化物浓度为128~1.13×103 mg/m3,非甲烷总烃浓度为(2.67~4.40)×105 mg/m3;经过“低温馏分油临界吸收-脱硫”净化后,硫化氢浓度低于3.0mg/m3,净化率大于99.9%,有机硫化物浓度低于0.6 mg/m3,净化率大于99.5%,非甲烷总烃浓度低于2.35×104 mg/m3,净化率大于95.1%。

Abstract: Fugitive odor emission behavior from sour water tanks and product intermediate tanks were comprehensively monitored and evaluated in a typical refinery. The comprehensive measures including reducing emissions of exhaust gas in tanks area and the absorbing process by low temperature distillate oils followed by desulfurization are used. The main odor pollutant in the tanks area is hydrogen sulfide, methyl mercaptan, ethyl mercaptan and dimethyl disulfide as well as non-methane hydrocarbons (NMHC). It is found that the hydrogen sulfide concentration in sour water tank is 175—3.36×103 mg/m3, organic sulfur compound concentration is 112-1.39×103 mg/m3, NMHC concentration is(2.67-4.40)×105 mg/m3. After purified by absorbing processe of low temperature distillate oils and then desulfurization, hydrogen sulfide concentration can be below 1 mg/m3, and purification efficiency reaches up to 99.9%. The organic sulfur compound concentration is less than 0.6mg/m3, and purification efficiency is greater than 99.5%. NMHC concentration is lower than 2.35×104 mg/m3, and purification efficiency reached as high as 95.1%.