石油炼制与化工 ›› 2018, Vol. 49 ›› Issue (12): 81-85.

• 分析与评定 • 上一篇    下一篇

柴油氧化安定性快速评定方法研究

孟凡坤,宋世远,钱述鹏,熊   

  1. 陆军勤务学院油料系
  • 收稿日期:2018-04-17 修回日期:2018-05-16 出版日期:2018-12-12 发布日期:2019-01-03
  • 通讯作者: 孟凡坤 E-mail:849871355@qq.com
  • 基金资助:
     

RAPID DETERMINATION OF DIESEL OXIDATION STABILITY

    

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  • Received:2018-04-17 Revised:2018-05-16 Online:2018-12-12 Published:2019-01-03
  • Supported by:
     

摘要: 为建立一种简便、快速评定柴油氧化安定性的方法,研制了一种新型柴油氧化安定性评定仪并确定了以氧化诱导期和氧化拐点作为氧化安定性的表征量。通过单因素分析和正交试验研究了影响柴油氧化安定性的因素,确定了最佳实验条件为温度140 °C,试样量70 mL,氧压700 kPa;建立了表征量与140 °C可滤出不溶物之间的相关性模型。结果表明,氧化拐点对140 °C可滤出不溶物的预测效果良好,该方法具有良好的重复性与区分性,能够较好地评定柴油氧化安定性。

关键词: 柴油, 氧化安定性, 正交试验, 相关性

Abstract: To establishing a simple and rapid method for determining diesel oxidation stability, a new type of instrument was developed, the oxidation induction period and oxidation inflection point were used as the symbol of oxidation stability. By means of the single-factor test and orthogonal test, the factors that impact on the diesel oxidation stability are explored. The optimal experimental conditions for the new instrument are 140℃,and O2 pressure of 700kPa. Meanwhile, a correlation model between the filterable insoluble substance at 140°C and the symbol was established. The results showed that the oxidation inflection point can be used to predict the filterable insoluble substance at 140°C. The method has good repetition and differentiation and can be used for evaluation of diesel oxidation stability.

Key words: diesel, oxidation stability, orthogonal test, correlation

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