石油炼制与化工 ›› 2019, Vol. 50 ›› Issue (5): 39-44.

• 加工工艺 • 上一篇    下一篇

重整原料掺入焦化汽油后预加氢工艺优化研究

马宝利,徐铁钢 ,韩志波, 张文成, 孙发民   

  1. 中国石油石油化工研究院大庆化工研究中心
  • 收稿日期:2018-09-05 修回日期:2018-11-19 出版日期:2019-05-12 发布日期:2019-05-28
  • 通讯作者: 马宝利 E-mail:mbl459@petrochina.com.cn
  • 基金资助:
    国家重点研发计划资助

OPTIMIZATION OF PRE-HYDROGENATION PROCESS FOR REFORMING FEED WITH COKER NAPHTHA

  1.  
  • Received:2018-09-05 Revised:2018-11-19 Online:2019-05-12 Published:2019-05-28
  • Contact: MA Bao-Li E-mail:mbl459@petrochina.com.cn
  • Supported by:
     

摘要: 针对重整原料掺入焦化汽油后对预加氢装置的影响,采用200 mL 中试加氢装置评价及响应曲面设计方法对主要影响因素进行研究,结果表明重整原料掺入15 %(w)焦化汽油后预加氢的最优工艺条件为反应温度287 ℃、反应压力2.0 MPa、体积空速2.0 h-1、氢油体积比200;主要影响因素中反应温度及反应压力的影响程度较大;通过Design expert软件得到生成油硫氮模型方程的预测值与实验值的相对误差小于5%,采用模型方程能够准确预测不同工况下的生成油硫氮含量,为重整预加氢工业装置掺炼焦化汽油后的工艺条件优化提供技术支持。

关键词: 催化重整, 焦化汽油, 工艺优化, 响应曲面设计

Abstract: The blending of reformer feed with coker naphtha increases the difficulty of pre-hydrogenation operation. The main factors affecting the process were investigated in a 200mL pilot plant by response surface design. The results of response surface interaction indicated that the reaction temperature and pressure had a greater influence on the removal of impurities. The optimum process conditions for pre-hydrogenation were temperature of 287 ℃, pressure of 2.0 MPa,LHSV of 2.0 h-1,and hydrogen/oil volume ratio of 200 when the feed contained 15% coker naphtha. Using the Design expert software,the relative error between the predicted value and the experimental value of the model equation is less than 5%. The model equation can accurately simulate the sulfur and nitrogen content of the oil produced under different operating conditions and provide technical support for the optimization of industrial process conditions.

Key words: catalytic reforming, coker naphtha, process optimization, response surface methodology

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