曼尼希碱燃油清净剂的结构及性能研究

石油炼制与化工 ›› 2019, Vol. 50 ›› Issue (11): 61-65.

曼尼希碱燃油清净剂的结构及性能研究

辛世豪,黄作鑫

中国石化石油化工科学研究院

收稿日期:2019-05-08 修回日期:2019-07-03 出版日期:2019-11-12 发布日期:2019-11-29
通讯作者: 辛世豪 E-mail:xinshihao.ripp@sinopec.com
基金资助:

STUDY ON STRUCTURE AND PERFORMANCE OF MANNICH DETERGENTS

Xin Shihao,Huang Zuoxin

SINOPEC Research Institute of Petroleum Processing

Received:2019-05-08 Revised:2019-07-03 Online:2019-11-12 Published:2019-11-29
Contact: Xin Shihao E-mail:xinshihao.ripp@sinopec.com
Supported by:

摘要/Abstract

摘要： 合成了不同结构的曼尼希碱清净剂，在汽油、柴油中进行了清净性能评价，探讨了曼尼希碱分子结构、热稳定性、增溶能力及分子键能与清净性能的关系。结果表明：Mono型和Bis型曼尼希碱的清净性能较好，Diamine型曼尼希碱清净效果较差；提高曼尼希碱胺化物中氮原子数无法进一步提高其清净性能；曼尼希碱热稳定性越高，清净性能越好，热稳定性相当时，增溶能力越强，清净性越好；曼尼希碱分子中仲胺生成的碳氮键键能小于伯胺生成的碳氮键键能，在高温时容易断裂而导致曼尼希碱清净性能变差。

关键词: 曼尼希碱, 燃油清净剂, 分子结构, 性能研究

Abstract: Mannich base detergents with different structures were synthesized and their detergency properties for gasoline and diesel fuel were evaluated. The relationship between the molecular structure, thermal stability, solubilization and bond energy of Mannich base with detergency property was discussed. The results showed that Mono and Bis Mannich base had better detergencies, but Diamine had worse detergency. Increasing the number of nitrogen atom in Mannich base amines could not further improve its cleaning performance. The higher the thermal stability of Mannich base, the better the cleaning performance. When the thermal stability was equal, the stronger the solubility, the better the cleanliness. The carbon-nitrogen bond energy generated by secondary amine in Mannich base molecule was less than that generated by primary amine, and it is easy to break at high temperature, resulting in poor cleaning performance of mannich base.

Key words: Mannich base, fuel detergent, molecular structure, performance study

中图分类号:

辛世豪黄作鑫. 曼尼希碱燃油清净剂的结构及性能研究[J]. 石油炼制与化工, 2019, 50(11): 61-65.

Xin Shihao Huang Zuoxin. STUDY ON STRUCTURE AND PERFORMANCE OF MANNICH DETERGENTS[J]. Petroleum Processing and Petrochemicals, 2019, 50(11): 61-65.

参考文献

[1]赵文柱, 和穆, 董芮寒, 等.柴油机喷油器喷孔积碳形成及影响研究进展[J].装甲兵工程学院学报, 2016, 30(04):46-52 [2]朱仁成, 鲍晓峰, 贾明, 等.汽油清净剂对汽车尾气排放影响及其清净性研究[J].环境工程技术学报, 2016, 6(04):307-313 [3]李泽振, 熊云.柴油清净剂的研究进展与应用概况[J].当代化工, 2018, 47(01):190-193 [4]璩洁荷, 戴泽青, 葛圣才.曼尼希胺在汽油清净剂中的应用性能及评价[J].山东化工, 2018, 47(20):94-97 [5]蔺建民，朱同荣，林滨，等.曼尼希碱无灰分散剂的合成及其在燃料中的应用[J].石油学报石油加工, 2006, 22(12):57-62 [6] 邢学永, 肖国光, 马国琪.曼尼希燃油添加剂的研究与应用技术进展[J].化工设计通讯, 2006, (01):54-56+60+62 [7] Lange A, Rath H P, Posselt D, et al.Method for producting mannich adducts that contain polyisobutylene phenol[P]. US8016898, 2011-09-13 [8] 田高友, 熊春华, 张德民.进气阀沉积物模拟试验方法应用研究[J].车用发动机, 2007, (2):89-92 [9]崔永胜.柴油清净剂的性能评价[J].石油商技, 2017, 35(06):32-35 [10] 万道正.曼尼希反应和曼尼希碱化学[M]. 科学出版社, 1986: 17-28 [11] Malcolm G J，McAtee R J，etal.Ortho-Alkylphenol derived mannich detergent composition and concentrate，fuel and method thereof[[J].US 2004/0168364A1, 2004-09-02, :- [12]Malfer D J.Mannich detergents for hydrocatbon fuels[J].US 2008/0141583A1, 2008-06-19, :- [13]Watanable H.Studies on the mechanism of solubilization action of succinimide[J].Bulletin of the Japanese Petroleum Institute, 1971, 13(2):250-258 [14]ZHENG X, ZHU H, KOSASIH B, et al.A molecular dynamics simulation of boundary lubrication ：The effect of n-alkanes chain length and normal load[J].Wear, 2013, 301(1-2):62-69