石油炼制与化工 ›› 2022, Vol. 53 ›› Issue (5): 36-39.

• 催化剂 • 上一篇    下一篇

催化裂化原料加氢处理催化剂PHF-311的工业应用

李军令1,夏恩冬2,王刚2,刘兵1,陈军1,吴显军2   

  1. 1. 中国石油独山子石化分公司
    2. 中国石油石油化工研究院大庆化工研究中心
  • 收稿日期:2021-11-23 修回日期:2022-01-14 出版日期:2022-05-12 发布日期:2022-04-24
  • 通讯作者: 李军令 E-mail:1405211811@qq.com
  • 基金资助:
    中国石油天然气股份有限公司重大技术现场试验项目(2019F-22)

COMMERCIAL APPLICATION OF PHF-311 CATALYST FOR FCC FEEDSTOCK HYDROTRERATING

  • Received:2021-11-23 Revised:2022-01-14 Online:2022-05-12 Published:2022-04-24

摘要: 中国石油石油化工研究院针对催化裂化原料预处理所研发的PHF-311加氢催化剂,于2019年9月在中国石油独山子石化分公司1.0 Mt/a蜡油加氢装置上成功应用。标定结果表明,在反应温度358.5 ℃、反应压力10.9 MPa、氢油体积比699、主剂体积空速0.94 h-1的工艺条件下,加氢蜡油的硫质量分数为493 μg/g,氮质量分数为474.8 μg/g,残炭为0.15%,是优质的催化裂化原料;加氢柴油的硫质量分数为6.2 μg/g,氮质量分数为30.8 μg/g,可作为柴油调合组分。从装置运行情况可以看出,PHF-311催化剂表现出较高的加氢脱硫、脱氮及降残炭活性,能够满足企业对清洁燃料生产的要求。

关键词: 催化裂化, 减压蜡油, 加氢处理, 催化剂

Abstract: The hydrotreating catalyst PHF-311 developed by PetroChina Research Institute of Petrochemical Technology for FCC feedstock pretreatment was successfully applied in the 1.0 Mt/a gas oil hydrotreating unit of PetroChina Dushanzi Petrochemical Company in September 2019. The calibration results show that under the process conditions of a reaction temperature of 358.5 ℃ ,a reaction pressure of 10.9 MPa, a volume ratio of hydrogen to oil of 699, a space velocity for main agent of 0.94 h-1, the gas oil with sulfur mass fraction of 493 μg/g and nitrogen mass fraction of 474.8 μg/g, and carbon residue of 0.15% can be obtained, which is a high-quality catalytic cracking feedstock. The hydrotreated diesel with 6.2 μg/g of sulfur and 30.8 μg/g of nitrogen can be used as diesel blending component. From the operation of the unit, it could be seen that PHF-311 catalyst had higher activities of hydrodesulfurization, hydrodenitrification and residue carbon reduction, which could meet the requirements of enterprises for clean fuel production.

Key words: catalytic cracking, vacuum gas oil, hydrotreating, catalyst