石油炼制与化工 ›› 2022, Vol. 53 ›› Issue (12): 59-64.

• 基础研究 • 上一篇    下一篇

气溶胶法炭负载纳米零价铁吸附与化学还原性能研究

郑玥石,占敬敬   

  1. 大连理工大学海洋科学与技术学院
  • 收稿日期:2022-03-23 修回日期:2022-08-11 出版日期:2022-12-12 发布日期:2022-12-06
  • 通讯作者: 郑玥石 E-mail:535945190@qq.com
  • 基金资助:
    国家自然科学基金

ADSORPTION AND CHEMICAL REDUCTION PERFORMANCE OF CARBON-SUPPORTED NANO-ZERO VALENT IRON PREPARED BY AEROSOL METHOD

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  • Received:2022-03-23 Revised:2022-08-11 Online:2022-12-12 Published:2022-12-06
  • Contact: Yue-Shi ZHENG E-mail:535945190@qq.com

摘要: 纳米零价铁(nZVI)作为一种新型环境友好材料,因其本身不稳定、易团聚等性质而在环境污染治理等领域的应用受到限制。本研究采用气溶胶法以炭作为载体,通过支撑与负载作用制备了炭负载纳米零价铁(Fe0/C)复合材料,并对其进行了系列表征,研究了其对有机物吸附和对硝酸盐的还原效果。结果表明:在Fe0/C 中,Fe0呈纳米颗粒状均匀镶嵌在球状炭球内外表面,直径范围为80~120 nm;相比nZVI,Fe0/C具有较高的比表面积;Fe0/C对罗丹明B的最大吸附量为853.7 mg/g,对硝酸盐的2 h去除率为50.6%,产物中54.7%为N2,表明复合材料具有良好还原性能与实际应用价值。

关键词: 气溶胶法, 纳米零价铁, 炭载体, 吸附, 还原

Abstract: Nano zero-valent iron (nZVI), as a new type of environmentally friendly material, is limited in the field of environmental pollution control due to its inherent instability and easy agglomeration. In this study, nano-zero-valent iron/carbon(Fe0/C) composites were prepared by using aerosol carbon as a carrier, and their effects on organic matter adsorption and nitrate reduction were studied. SEM results show that Fe0 is uniformly embedded in the inner and outer surfaces of spherical carbon in the form of nanoparticles, with a diameter ranging from 80 to 120 nm. Combined with BET and other characterization results, it is shown that Fe0/C composite has a high specific surface area. The results of adsorption and chemical reduction experiments showed that the maximum adsorption capacity of Rhodamine B was 853.7 mg/g, the removal rate of nitrate for 2 h was 50.6%, and 54.7% of the product was nitrogen, which proved the good reduction performance and practical application value of the composite material.

Key words: aerosol method, nano-zero valent iron, carbon support, adsorption, reduction