脂肪醇胺化反应非均相催化剂研究进展

摘要/Abstract

摘要： 脂肪胺作为一种重要的精细化学中间体，广泛应用于染料、农药等领域。醇还原胺化制胺反应具有原料来源广泛、工艺简单、绿色经济等优点，是目前最具工业前景的方法之一，其催化剂的开发是该反应的关键与难点。基于此，综述了脂肪醇胺化反应非均相催化剂的研究进展，介绍了Ni，Co，Pd，Ru 等4类催化剂用于不同底物的催化性能和反应规律，论述了提高催化剂性能的主要手段为修饰金属（几何结构、电子结构）和载体（酸碱性、金属?载体相互作用）位点，提出了未来研究的重点在于高性能催化剂制备、反应机理及构效关系研究、温和反应体系以及多元醇体系开发。

关键词: 脂肪醇, 还原胺化, 绿色合成, 催化剂

Abstract: As an important fine chemical intermediate, aliphatic amines are widely used in dyes, pesticides and other fields. The reductive amination of alcohol is one of the most promising methods with wide source of raw materials, simple process and green economy. The development of catalyst is the key and difficult point of the reaction. The research progress in heterogeneous catalysts for amination of fatty alcohol was reviewed, and the catalytic performance and reaction regularity of Ni, Co, Pd and Ru catalysts for different substrates were introduced. The modification of metal (such as its geometric structure, its electronic structure) and support (acid-base, metal-support interaction) sites were described as the main means to improve the performance of catalysts. The frontiers of the topic, including the preparation of high performance catalysts, the study of reaction mechanism and structure-activity relationship, and the development of mild reaction and polyols systems, were put forward.

Key words: fatty alcohol, reductive amination, green synthesis, catalyst

王诗晴孙斌赵俊琦李昕张晓昕. 脂肪醇胺化反应非均相催化剂研究进展[J]. 石油炼制与化工, 2023, 54(7): 137-144.

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