石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (6): 156-165.

• 综述 • 上一篇    下一篇

催化裂化增产低碳烯烃催化剂及助剂研究进展

刘雨晴,于善青,孙敏,宋海涛   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2024-09-19 修回日期:2025-01-13 出版日期:2025-06-12 发布日期:2025-05-30
  • 通讯作者: 于善青 E-mail:yusq.ripp@sinopec.com

RESEARCH PROGRESS ON CATALYSTS AND ADDITIVES FOR INCREASING LIGHT OLEFINS PRODUCTION IN FLUID CATALYTIC CRACKING UNIT


  • Received:2024-09-19 Revised:2025-01-13 Online:2025-06-12 Published:2025-05-30

摘要: 在催化裂化(FCC)过程中增产低碳烯烃是很多炼油厂优化产品结构、提高经济效益的有效手段,也是实现炼油向化工转型的重要途径之一。综述了近20年来国内外FCC增产低碳烯烃的催化剂和助剂产品及其技术特色,总结了部分产品在国内炼油厂的应用效果,以期为炼油厂选择适宜的增产低碳烯烃产品提供参考。增产低碳烯烃催化剂和助剂技术趋于成熟,未来,分子筛和基质性能的持续优化将是不变的主题,催化剂组装技术将在构建多层次贯通孔道的高可及性催化剂和助剂方面发挥重要作用。

关键词: 催化裂化, 低碳烯烃, 催化剂, 助剂, 汽油, 辛烷值, ZSM-5分子筛

Abstract: Increasing the production of light olefins in fluid catalytic cracking (FCC) unit is an effective mean for many refineries to optimize product distribution and enhance economic benefit. It is also one of the critical pathways to transform the refining industry towards the chemical industry.The catalysts and additives for enhancing light olefins production in FCC, along with their technological features, was reviewed over the past two decades both domestically and internationally. The applications of some products in domestic refineries were summarized, aiming to provide references for refineries in selecting suitable products to increase light olefins production. Currently, the technology for enhancing light olefins production is maturing, and the continued optimization of zeolite and matrix properties will be the unchanging theme in the future. Catalyst assembly technology may play a significant role in constructing highly accessible catalysts and additives with hierarchical pores.

Key words: catalytic cracking, light olefin, catalyst, additive, gasoline, octane number, ZSM-5 zeolite