石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (7): 179-185.

• 节能减排 • 上一篇    下一篇

延迟焦化含硫污水除油除焦粉技术的工业应用

简小文,刘林波   

  1. 深圳科力迩科技有限公司
  • 收稿日期:2024-11-12 修回日期:2025-01-21 出版日期:2025-07-12 发布日期:2025-07-01
  • 通讯作者: 刘林波 E-mail:1546957261@qq.com

COMMERCIAL APPLICATION OF COKE POWDER REMOVAL TECHNOLOGY FOR SULFUR-CONTAINING WASTEWATER FROM DELAYED COKING UNIT

  • Received:2024-11-12 Revised:2025-01-21 Online:2025-07-12 Published:2025-07-01

摘要: 鉴于现有焦化含硫污水的除油除焦粉技术处理效果不理想,易导致下游汽提装置发生结焦堵塞的问题,提出了一种新型的无药剂焦化含硫污水预处理工艺。该工艺以“旋流溶气气浮+聚结除油”技术为核心,辅以过滤去除焦粉。分析了该组合工艺的技术原理,并通过工业应用检验了其处理效果。结果表明:在延迟焦化非小吹汽阶段,该组合工艺的平均除油效率达到98.83%,在入口悬浮物平均质量浓度为353mg/L的条件下,出口悬浮物平均质量浓度为7mg/L;在延迟焦化小吹汽阶段,除油效率和悬浮物去除率均有不同程度提高。这说明,该组合工艺对延迟焦化含硫污水的除油和除焦粉效果优异,可为类似污水资源化处理提供有益借鉴。

关键词: 延迟焦化, 含硫污水, 焦粉, 旋流溶气气浮, 聚结除油

Abstract: In light of the inadequate treatment effectiveness exhibited by contemporary technologies in eradicating oil and coke powder from sulfur-containing wastewater, a phenomenon that has given rise to challenges concerning coking and blockage within downstream stripping units, this study proffers a novel chemical-free pretreatment process, predicated on the "cyclone dissolved air flotation + coalescence oil removal" technology. This process is further augmented by filtration mechanisms that are designed for the elimination of coke powder, thereby functioning as a pretreatment for the stripping apparatus. The experimental results demonstrate that, during the non-small steam blowing phase, the process achieves an average oil removal efficiency of 98.93%.The average mass concentration of suspended solids at the outlet is 7 mg/L. This is calculated using the average mass concentration of suspended solids at the inlet, which is 353 mg/L. In the small steam blowing phase, oil removal efficiency and suspended solids removal rate have been improved to different degrees. It is also notable that high-quality light pollution oil can be recycled and reused, providing a valuable reference for the effective treatment of similar wastewater.

Key words: delayed coking, sulfur-containing wastewater, coke powder, cyclonic dissolved air flotation, coalescence oil removal