石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (11): 59-64.

• 加工工艺 • 上一篇    下一篇

C5/C6异构化装置产品优化与运行分析

冯连坤1,陈晓华2,王志春1   

  1. 1. 中石油云南石化有限公司
    2. 中国石油兰州石化公司
  • 收稿日期:2025-04-21 修回日期:2025-07-09 出版日期:2025-11-12 发布日期:2025-10-24
  • 通讯作者: 冯连坤 E-mail:fengliankun@petrochina.com.cn

OPERATION ANALYSIS AND PRODUCT OPTIMIZATION OF C5/C6 ISOMERIZATION UNIT

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  • Received:2025-04-21 Revised:2025-07-09 Online:2025-11-12 Published:2025-10-24

摘要: 对以重整拔头油和芳烃抽余油为原料生产汽油调合组分的C5/C6异构化装置进行优化调整,将含正构烷烃的13~18 t/h抽余油分馏塔塔底C7+组分改至催化裂化装置,将脱己烷塔塔底含环己烷组分送至催化重整装置。结果表明:在双苯抽提工况下,优化调整后,催化裂化装置可增产丙烯0.5~1.2 t/h,催化重整装置可增产苯0.3~0.4 t/h,C5/C6异构化产品研究法辛烷值(RON)从80.4升至84.6,饱和蒸气压从85.7 kPa增至104.9 kPa,全厂汽油池RON从93.82升至94.39,装置能耗从41.30 kgOE/t(1 kgOE=41.8 MJ)降至21.09 kgOE/t,实现了减油增化、节能降耗的目的。

关键词: 异构化, C6, C7, 辛烷值, 正构烷烃, 丙烯

Abstract: The C5/C6 isomerization unit which used reforming topped oil and aromatics extraction raffinate as raw materials for gasoline blending components were adjusted. The C7+ components from the bottom of the extractive distillation tower with 13—18 t/h which contain normal alkane were sented to FCC unit. The cyclohexane components from the bottom of the de-hexane tower were sented to the catalytic reforming unit. The results showed that under the condition of dual benzene extraction process, after the operation parameters were optimized and adjusted, the FCC unit increased propylene production by 0.5—1.2 t/h, the catalytic reforming unit increased benzene production by 0.3—0.4 t/h, the RON of the isomerization product increased from 80.4 to 84.6 and the vapor pressure increased from 85.7 kPa to 104.9 kPa, the RON of the gasoline pool increased from 93.82 to 94.39. The energy consumption of the unit reduced from 41.30 kgOE/t(1 kgOE=41.8 MJ) to 21.09 kgOE/t. The goals of reducing oil and increasing chemicals, as well as energy conservation and consumption reduction were achieved.

Key words: isomerization, C6, C7, octane number, alkane, propylene