石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (5): 136-143.

• 节能减排 • 上一篇    下一篇

耦合绿氢的石油焦制烯烃工艺经济性与碳减排分析

陈渤燕,李庆勋,钟海军,王月,李昊龙,李子贤,张学瑞   

  1. 中国石油石油化工研究院
  • 收稿日期:2025-11-07 修回日期:2026-01-09 出版日期:2026-05-12 发布日期:2026-04-24
  • 通讯作者: 陈渤燕 E-mail:chenboyan@petrochina.com.cn
  • 基金资助:
    中国石油科技管理部基础性前瞻性科技专项

ANALYSIS OF THE ECONOMICS AND CARBON EMISSION REDUCTION OF A GREEN HYDROGEN-INTEGRATED PETROLEUM COKE TO OLEFINS PROCESS


  • Received:2025-11-07 Revised:2026-01-09 Online:2026-05-12 Published:2026-04-24

摘要: 为实现炼油厂副产石油焦的高值化与低碳化利用,提出了石油焦气化-甲醇-烯烃制取低碳烯烃的技术路径,构建了传统路线与绿氢补氢路线两种工艺方案,并对其能耗、经济性及碳减排潜力进行了综合分析。研究表明,传统路线在当前市场环境下具备竞争力,绿氢补氢路线通过流程优化和碳资源循环利用,在能耗和碳减排方面均显著优于传统路线,可大幅提升烯烃产量,并随绿电电价下降呈现跨越式竞争力。相较于石油焦直接燃烧,两种路线均能实现显著碳减排,其中绿氢补氢路线趋近零排放。该技术具备规模化消纳风光电力、同步生产基础化学品的双重功能,为炼化行业实现资源高效利用和低碳转型提供了重要的数据支撑和决策参考。

关键词: 石油焦, 能耗, 甲醇制烯烃, 可再生能源电力, 碳减排

Abstract: To achieve high-value and low-carbon utilization of refinery by-product petroleum coke, this study proposes a technical route for producing light olefins via petroleum coke gasification-methanol-olefins process. Two process schemes—a conventional route and a green hydrogen-supplemented route—were constructed and comprehensively analyzed in terms of energy consumption, economic performance, and carbon reduction potential. The results indicate that the conventional route is already competitive under current market conditions, while the green hydrogen-supplemented route significantly outperforms the conventional one in terms of energy efficiency and carbon emission reduction through process optimization and carbon resource recycling. This route also substantially increases olefin production and exhibits leapfrog competitiveness as the cost of renewable electricity decreases. Compared with direct combustion of petroleum coke, both routes achieve significant carbon reduction, with the green hydrogen-supplemented route approaching near-zero emissions. This technology demonstrates the dual function of large-scale integration of wind and solar power and simultaneous production of bulk chemicals, providing important data support and decision-making reference for the petrochemical industry in achieving efficient resource utilization and low-carbon transition.

Key words: petroleum coke, energy consumption, methanol to propylene, renewable electricity, carbon emissions